Reactions of RȮ, RṠ, and RȮ<sub>2</sub>Radicals with Phosphites and Phosphines

Pobedimskii, D. G.; Mukmeneva, N. A.; Kirpichnikov, P A

doi:10.1070/rc1972v041n07abeh002076

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1988

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Cited by 10 publications

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“…This is in excellent agreement with the value obtained from rates of autoxidation of toluene in the presence of E-butyl hydroperoxide [S2].F. Trivalent phosphorus compoundsTrivalent phosphorus compounds react with molecular oxygen, particularly in the presence of free-radical initiators, to give pentavalent oxygenated products[53][54][55][56]. These reactions are complex free-radical chain reactions and kinetic studies have met with limited success.…”

supporting

confidence: 70%

The application of kinetic electron spin resonance spectroscopy to some reactions oft-butylperoxyl in solution

Howard

1984

Res Chem Intermed

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supporting

confidence: 70%

The application of kinetic electron spin resonance spectroscopy to some reactions oft-butylperoxyl in solution

Howard

1984

Res Chem Intermed

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The Decomposition of Alkyl Nitrites and the Reactions of Alkoxyl Radicals

Heicklen

1988

Advances in Photochemistry

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Gas phase kinetic study of the thermal reactions of t‐butoxy radicals with germane, phosphine, and trimethylsilane

Lee¹,

Choo²

1986

Int J of Chemical Kinetics

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The hydrogen abstraction reactions of tert-butoxyl radicals with germane, phosphine, and trimethylsilane were studied by pyrolyzing di-t-butyl peroxide in the temperature range of 403 to 458 K. From the reported rate constant for the tert-butoxy radical decomposition in the literature, the absolute rate constants were determined from the study of competitive reaction between t-butoxy radical decomposition (t-BuO decompose+ CH3COCH3 + CH,) and hydrogen abstraction reaction. (t-BuO RH -+ t-BuOH + R, where RH = GeH,, PH,, and HSiMe,)The Arrhenius parameters are found to be as follows:E,(kcal mol-') Log A t-BuO + SiHMe, 2.1 t-BuO + GeH, 1.9t-BuO + PH3

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Reactions of RȮ, RṠ, and RȮ₂Radicals with Phosphites and Phosphines

Cited by 10 publications

References 1 publication

The application of kinetic electron spin resonance spectroscopy to some reactions oft-butylperoxyl in solution

The application of kinetic electron spin resonance spectroscopy to some reactions oft-butylperoxyl in solution

The Decomposition of Alkyl Nitrites and the Reactions of Alkoxyl Radicals

Gas phase kinetic study of the thermal reactions of t‐butoxy radicals with germane, phosphine, and trimethylsilane

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Reactions of RȮ, RṠ, and RȮ2Radicals with Phosphites and Phosphines

Cited by 10 publications

References 1 publication

The application of kinetic electron spin resonance spectroscopy to some reactions oft-butylperoxyl in solution

The application of kinetic electron spin resonance spectroscopy to some reactions oft-butylperoxyl in solution

The Decomposition of Alkyl Nitrites and the Reactions of Alkoxyl Radicals

Gas phase kinetic study of the thermal reactions of t‐butoxy radicals with germane, phosphine, and trimethylsilane

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Product

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Reactions of RȮ, RṠ, and RȮ₂Radicals with Phosphites and Phosphines