Reactions of the solvated proton system H+ - [(CH3)2CO]n formed in photoionization of acetone

Łuczyński, Z.; Wincel, H.

doi:10.1016/0020-7381(77)80005-3

Cited by 19 publications

(5 citation statements)

References 9 publications

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“…Reaction (2) has been reported by many researchers (40)(41)(42) The unimolecular dissociation reactions observed in these experiments are shown in Table II. A few of the reactions are worth further discussion.…”

Section: A Studies Of Bonding and Kinetic Energy Releasesupporting

confidence: 60%

Studies of the formation, chemical reactivity, and properties of small clusters: Application to an understanding of aerosol formation and heterogeneous chemistry

Castleman¹

1990

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This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, compietene._s, or usefulness of any information, apparatus, product, or procer_ disclosed, or represents that its use would not infringe privately owned rights. Reference herein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise does not necessarily constitute or imply its endorsement, recommendation, or favoring by the United States Government or any agency thereof. The views and opinions of authors expressed herein do not necessarily state or reflect those of the United States Government or any agency thereof.

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Section: A Studies Of Bonding and Kinetic Energy Releasesupporting

confidence: 60%

Studies of the formation, chemical reactivity, and properties of small clusters: Application to an understanding of aerosol formation and heterogeneous chemistry

Castleman¹

1990

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“…Another particularly revealing finding comes from studies of acetone clusters upon their ionization. − The reaction for certain specific protonated clusters can lead to the production of an acetyl cluster ion solvated by acetone. This arises due to a dehydration mechanism which, interestingly, is found to be totally suppressed when the clusters are prehydrated, demonstrating the influence of solvation blocking on the reaction site.…”

Section: Cluster Kinetics and Dynamicsmentioning

confidence: 99%

Clusters: Structure, Energetics, and Dynamics of Intermediate States of Matter

1996

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The field of cluster research can trace its origins back to the mid-nineteenth century when early studies of colloids, aerosols, and nucleation phenomena were reported. The field underwent a resurgence of interest several decades ago when well-defined clusters were observed in supersonic expansions that could be investigated using mass spectrometers. The advent of the laser provided a new dimension, enabling detailed spectroscopic observations through the probing of systems of varying size and degree of solvation. Modern interest derives from recognition that interrogating clusters provides a way of studying the energetics and dynamics of intermediate states of matter as cluster systems evolve from the gas toward the condensed state. Herein, we endeavor to highlight some of the significant advances which have been made during the past several decades that have led to a nearly explosive growth of interest in the field of cluster science. Finally, we conclude that the field will continue to expand through interests in basic phenomena, as well as through numerous applications of cluster research to fields ranging from catalysis to the quest for new cluster-assembled materials.

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“…Several studies of proton-bound clusters of acetone have been reported using mass spectrometers. [11][12][13][14][15] Both electron impact 13 and photoionization 11 of neutral acetone clusters produced ionic complexes of the form H + (C 3 H 6 O) n . Multiple isomers of H + (C 3 H 6 O) 2 have been implicated in many of these studies, although with conflicting results.…”

mentioning

confidence: 99%

The structure of protonated acetone and its dimer: infrared photodissociation spectroscopy from 800 to 4000 cm⁻¹

Douberly

Ricks

Ticknor

et al. 2008

Phys. Chem. Chem. Phys.

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Reactions of the solvated proton system H+ - [(CH3)2CO]n formed in photoionization of acetone

Cited by 19 publications

References 9 publications

Studies of the formation, chemical reactivity, and properties of small clusters: Application to an understanding of aerosol formation and heterogeneous chemistry

Studies of the formation, chemical reactivity, and properties of small clusters: Application to an understanding of aerosol formation and heterogeneous chemistry

Clusters: Structure, Energetics, and Dynamics of Intermediate States of Matter

The structure of protonated acetone and its dimer: infrared photodissociation spectroscopy from 800 to 4000 cm⁻¹

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Reactions of the solvated proton system H+ - [(CH3)2CO]n formed in photoionization of acetone

Cited by 19 publications

References 9 publications

Studies of the formation, chemical reactivity, and properties of small clusters: Application to an understanding of aerosol formation and heterogeneous chemistry

Studies of the formation, chemical reactivity, and properties of small clusters: Application to an understanding of aerosol formation and heterogeneous chemistry

Clusters: Structure, Energetics, and Dynamics of Intermediate States of Matter

The structure of protonated acetone and its dimer: infrared photodissociation spectroscopy from 800 to 4000 cm−1

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The structure of protonated acetone and its dimer: infrared photodissociation spectroscopy from 800 to 4000 cm⁻¹