Reactions on single-walled nanotubes: 2. Reactions on the nanosized surface of nanotubes in liquid hydrocyanic acid

Reaction Acceleration in Thin Films with Continuous Product Deposition for Organic Synthesis

“…[2] Base-catalyzed Claisen-Schmidt condensation is accelerated in electrosprayed droplets, [3] in levitated Leidenfrost droplets, [4] and in the paper spray experiment that combines athin film format with charged droplet emission. [10] The underlying reasons for acceleration are increased reagent reactivity,d ue to partial desolvation at the interface, [11] pH value change, [12] and increased reagent concentration associated with solvent evaporation. [10] The underlying reasons for acceleration are increased reagent reactivity,d ue to partial desolvation at the interface, [11] pH value change, [12] and increased reagent concentration associated with solvent evaporation.…”

“…[5] Many other reactions involving C À H, [6] C À C, [2][3][4][5]7] C À N, [2,8] and CÀO [9] bond formation have been reported to be accelerated by factors of 10-10 6 in confined volumes. [10] The underlying reasons for acceleration are increased reagent reactivity,d ue to partial desolvation at the interface, [11] pH value change, [12] and increased reagent concentration associated with solvent evaporation. [13] Hour-long reactions can be performed in minutes in these mass-spectrometry-informed syntheses.…”

Laser Raman micro-spectroscopy as an effective non-destructive method of detection and identification of various sp2 carbon modifications in industry and in nature

“…Fig. 14exemplifies this by presenting our results obtained for a SWNT bundle prepared by an electric arc method with use of a Ni/Y catalyst and purified to carbon content 95 %[72].…”