Reactive Polymer Coatings that “Click”

Nandivada, Himabindu; Chen, Hsien Yeh; Bondarenko, Lidija; Lahann, Joerg

doi:10.1002/anie.200600357

Cited by 193 publications

(165 citation statements)

References 36 publications

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“…Alkyne functionalised base layers and alkyne thiols are also potential candidates for plasmachemical thiol-ene click reactions. 66,67 Other variants include pulsed, downstream, and atmospheric plasmas for generation of the prerequisite thiyl radicals. Additional improvements in wet electrical barrier performance are envisaged by depositing a hydrophobic layer on top of the aforementioned multilayer structure in order to incorporate enhanced liquid repellency, Supporting Information …”

Section: Scalabilitymentioning

confidence: 99%

Plasmachemical Double Click Thiol–ene Reactions for Wet Electrical Barrier

Fraser

Carletto

Wilson

et al. 2016

ACS Appl. Mater. Interfaces

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The full-text may be used and/or reproduced, and given to third parties in any format or medium, without prior permission or charge, for personal research or study, educational, or not-for-prot purposes provided that:• a full bibliographic reference is made to the original source • a link is made to the metadata record in DRO • the full-text is not changed in any way The full-text must not be sold in any format or medium without the formal permission of the copyright holders.Please consult the full DRO policy for further details. ABSTRACTClick thiol-ene chemistry is demonstrated for the reaction of thiol containing molecules with surface alkene bonds during electrical discharge activation. This plasmachemical reaction mechanism is shown to be two-fold for allyl mercaptan (an alkene and thiol group containing precursor), comprising self-crosslinked nanolayer deposition in tandem with interfacial crosslinking to the surface alkene bonds of a polyisoprene base layer. A synergistic multilayer structure is attained which displays high wet electrical barrier performance during immersion in water.4

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Section: Scalabilitymentioning

confidence: 99%

Plasmachemical Double Click Thiol–ene Reactions for Wet Electrical Barrier

Fraser

Carletto

Wilson

et al. 2016

ACS Appl. Mater. Interfaces

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“…[1][2][3] There is a vast range of applications on the immobilization of biomolecules, such as biochips, [4][5][6] biosensors, [7,8] biocompatible materials, [9][10][11] and so on. [12][13][14] Polymers are often used as waterinsoluble supports to immobilize biomolecules, using covalent bonds, ionic bonds or physical adsorption. The surface modification of polymer is required to introduce reactive groups for the immobilization of biomolecules, in which there are several methods, such as coating, plasma surface treatment and photoirradiation.…”

Section: Introductionmentioning

confidence: 99%

Evaluation on Fluidity of the Self-Assembled Phospholipid Layer Fabricated by Plasma-Assisted Method and its Application

Kondo

Sasai

Yamauchi

et al. 2012

J. Photopol. Sci. Technol.

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“…[1][2][3][4] For example, the 1,3-dipolar cycloaddition of alkynes with organic azides on a surface has been known to be a pertinent method of connecting DNA, protein and fluorophores on the solid surface. [5][6][7][8] In particular, selectively immobilized alkynes on a surface can be useful to nanoarrays and nanopatternings of a surface. For the selective immobilization of alkynes on a surface, alkynes can be introduced by covalent bonding with the prearrayed functional group.…”

Section: Introductionmentioning

confidence: 99%

Synthesis and E-Beam-Mediated Gas Phase Fragmentation of Thiol-Containing Furoxans for Nanopatterned Alkyne Formation on Gold Surface

Koo¹,

Park²,

Hwang

2010

Bulletin of the Korean Chemical Society

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Furoxanthiols PFT and BPFT possessing thiomethyl or thiobenzyl groups in the furoxan ring were designed and synthesized as potential light-sensitive alkyne precursors on a gold surface. The synthesis of thiofuroxans PFT and BPFT was performed from the corresponding halofuroxans 1b and 2c, respectively, by the substitution with potassium thioacetate in ethyl acetate/ethanol or DMF, followed by basic hydrolysis as the key reactions. Electron-beammediated fragmentation of furoxans 1c and 2d in a mass spectrometer afforded the corresponding aryl alkyne fragments, with the evolution of NO in high preference. In the cases of thiofuroxans PFT and BPFT, carbon-sulfur bond cleavage was observed as a representative fragmentation, producing M-SH and M-SAc peaks, which competed with the release of NO. In the fragmentation of mono-aryl furoxan 1c, the release of molecule of NO was predominately observed to produce an M-NO fragment as a base peak by the formation of trimembered thiiranium or azirine intermediate.

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Reactive Polymer Coatings that “Click”

Cited by 193 publications

References 36 publications

Plasmachemical Double Click Thiol–ene Reactions for Wet Electrical Barrier

Plasmachemical Double Click Thiol–ene Reactions for Wet Electrical Barrier

Evaluation on Fluidity of the Self-Assembled Phospholipid Layer Fabricated by Plasma-Assisted Method and its Application

Synthesis and E-Beam-Mediated Gas Phase Fragmentation of Thiol-Containing Furoxans for Nanopatterned Alkyne Formation on Gold Surface

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