Reactivity and characteristics of Pd/MOF and Pd/calcinated-MOF catalysts for CO oxidation reaction: Effect of oxygen and hydrogen

Pd/Ni-metal–organic framework-derived porous carbon nanosheets for efficient CO oxidation over a wide pH range

“…The significant enhancement of the CO oxidation performance of Pd/Ni-MOF/PC plausibly originated from the porous 2D morphology and Pd/Ni–N x active sites. 38,43–47…”

“…, CO and O 2 ) and facilitate their diffusion to the inner cavities, which are highly stable against agglomeration. 38,43–47 In addition, the abundant active sites of Pd/Ni–N x embedded in MOF/PC allow the activation/dissociation of CO and O 2 along with facilitating the generation of oxygen species ( i.e. , OH) at low overpotentials.…”

“…38,43–47 There are a few reports on using MOFs and their derivatives as supports for Pd nanocrystals for thermal CO oxidation. 38,43–48 However, the electrochemical CO oxidation performance of MOF-based catalysts with or without Pd nanocrystals is not yet reported to the best of our knowledge. 38,43–47…”

“…38,43–48 However, the electrochemical CO oxidation performance of MOF-based catalysts with or without Pd nanocrystals is not yet reported to the best of our knowledge. 38,43–47…”

Enhanced photoreactivity of MOFs by intercalating interlayer bands via simultaneous NCO and SCu modification

“…The regular cavities and abundant pore structure of MOFs present unique advantages for doping strategies, 22 but the doping defects are also quite obvious. For example, doping with precious metals (e.g., palladium, 23 platinum, 24 and rhodium 25 ) could inevitably increase the cost of materials. Moreover, the high temperatures required for the partial doping reaction could increase energy consumption, and metal leakage poses the risk of secondary pollution 26 .…”