Reactivity control in palladium-catalyzed reactions: a personal account

Kočovský, Pavel

doi:10.1016/j.jorganchem.2003.07.008

“…Being inspired by the Katsuki P , N -ligand 3 , we have now studied the role of the analogous terpene-derived P , N -ligands 4 – 7 . The synthesis of (−)- 4 from (+)-Δ 2 -carene in five steps was described by us recently in connection with our studies on asymmetric Heck reaction and Pd(0)-catalyzed allylic substitution. , In the same paper we have also reported on the synthesis of the enantiomeric (−)- 6 from (−)-β-pinene or (−)-α-pinene, both in 4 steps . Using an analogous procedure and (+)-α-pinene as starting material, we have now prepared (+)- 5 , (+)- 6 , and (−)- 7 as follows (Scheme ).…”

Section: Resultsmentioning

confidence: 84%

Enantioselective Baeyer–Villiger Oxidation Catalyzed by Palladium(II) Complexes with Chiral P,N-Ligands

Malkov

¹

,

Friscourt

²

,

Bell

³

et al. 2008

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Mercury: Organometallic ChemistryBased in part on the article Mercury: Organometallic Chemistry by Richard C. Larock which appeared in the Encyclopedia of Inorganic Chemistry, First Edition .

Rais

¹

,

Vilar

²

2005

Encyclopedia of Inorganic Chemistry

2

0

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Over the past 10 years, a wide range of new organomercury compounds have been prepared and their reactivity extensively studied, leading to interesting applications in organic synthesis. The solvomercuration of alkenes is still the most widely employed organometallic reaction of mercury, although there have been important advances in the use of the mercury‐mediated ring opening of cyclopropanes. Several structural investigations of organomercurials have been recently carried out providing detailed information on the connectivity of a wide range of mono‐ and polymercuric complexes. In this article, an overview of the most important advances on the organometallic chemistry of mercury between 1993 and 2003 will be provided.

show abstract

Mercury: Organometallic ChemistryBased in part on the article Mercury: Organometallic Chemistry by Richard C. Larock which appeared in the Encyclopedia of Inorganic Chemistry, First Edition .

Rais

¹

,

Vilar

²

2005

Encyclopedia of Inorganic and Bioinorganic Chemistry

1

0

View full text Add to dashboard Cite

Over the past 10 years, a wide range of new organomercury compounds have been prepared and their reactivity extensively studied, leading to interesting applications in organic synthesis. The solvomercuration of alkenes is still the most widely employed organometallic reaction of mercury, although there have been important advances in the use of the mercury‐mediated ring opening of cyclopropanes. Several structural investigations of organomercurials have been recently carried out providing detailed information on the connectivity of a wide range of mono‐ and polymercuric complexes. In this article, an overview of the most important advances on the organometallic chemistry of mercury between 1993 and 2003 will be provided.

show abstract

Reactivity control in palladium-catalyzed reactions: a personal account

Cited by 22 publications

References 106 publications

Enantioselective Baeyer–Villiger Oxidation Catalyzed by Palladium(II) Complexes with Chiral P,N-Ligands

Enantioselective Baeyer–Villiger Oxidation Catalyzed by Palladium(II) Complexes with Chiral P,N-Ligands

Mercury: Organometallic ChemistryBased in part on the article Mercury: Organometallic Chemistry by Richard C. Larock which appeared in the Encyclopedia of Inorganic Chemistry, First Edition .

Mercury: Organometallic ChemistryBased in part on the article Mercury: Organometallic Chemistry by Richard C. Larock which appeared in the Encyclopedia of Inorganic Chemistry, First Edition .

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