Reactivity of 1,4-Diaza-1,3-Butadienes towards Cu(II) Pivalate: A Rare Case of Polymeric Structure Formed by Bridging Diazabutadiene Ligands

Voronina, Julia K.; Gavronova, A. S.; Yambulatov, D. S.; Николаевский, С. А.; Кискин, М. А.; Еременко, И. Л.

doi:10.1134/s1070328422700154

Cited by 3 publications

(1 citation statement)

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“…Coordination polymers are formed by binding metal ions or metal-containing cores with bridging ligands, whose variation in structure-forming parameters allows for control over the polymer's structure [1][2][3][4][5][6][7][8][9][10], as well as luminescent [11][12][13][14], sorption [4,[15][16][17][18], magnetic [19][20][21][22], and other properties. Iron(II) coordination polymers exhibit selective catalytic activity in the hydroboration of aldehydes and ketones [23], the oxidative functionalization of alkanes [24], and in dimerization reactions of aromatic halogen derivatives [25].…”

Section: Introductionmentioning

confidence: 99%

Coordination Polymer Based on a Triangular Carboxylate Core {Fe(μ3-O)(μ-O2CR)6} and an Aliphatic Diamine

Bushuev,

Gogoleva,

Nikolaevskii

et al. 2024

Molecules

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Interaction of the pre-organized complex of iron(II) trimethylacetate and 1,10-phenanthroline (phen) [Fe2(piv)4(phen)2] (1) (piv = (Me)3CCO2−)) with 1,6-diaminohexane (dahx) in anhydrous acetonitrile yielded a 1D coordination polymer [Fe3O(piv)6(dahx)1.5]n (2) and an organic salt of pivalic acid (H2dahx)(piv)2 (3). The structure of the obtained compounds was determined by single-crystal X-ray diffraction analysis. The phase purity of the complexes was determined by powder X-ray diffraction analysis. According to the single-crystal X-ray analysis, coordination polymer 2 is formed due to the binding of a triangular carboxylate core {Fe3(μ3-O)(μ-piv)6} with an aliphatic diamine ligand. Thermal behavior was investigated for compounds 1 and 2 in an argon atmosphere.

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