Reactivity of azido terpyridine Pd(ii) and Pt(ii) complexes towards 4,4,4-trifluoro-2-butynoic acid: structural insight into the triazolato coordination mode

Abstract

The binuclear azido terpyridine Pd(ii) complex underwent the catalyst-free cycloaddition coupling with alkyne affording triazolate analogues. The coordination mode of the triazolate ring was assigned with the aid of quantum chemical calculations.