<p><strong>Abstract.</strong> Studies of detailed chemical compositions in particles with different size ranges emitted from ships are in serious shortage. In this study, size-segregated distributions and characteristics of particle mass, organic carbon (OC), elemental carbon (EC), 16 EPA PAHs and 25 n-alkanes measured on board of 12 different vessels in China were given. The results showed that: (1) More than half of the total particle mass, OC, EC, PAHs and n-alkanes were concentrated in fine particles with aerodynamic diameter (D<sub>p</sub>)&#8201;<&#8201;1.1&#8201;&#956;m for most of the tested ships, basically presenting downward distribution trends with the increase of particle size. However, different types of ships showed quite different particle size-dependent chemical compositions. (2) In fine particles, the OC and EC were the dominant components, while in coarse particles, OC and EC only accounted for very small proportions. With the increase of particle size, the OC to EC ratios first decreased and then increased, having the lowest values for particle sizes between 0.43&#8201;&#956;m and 1.1&#8201;&#956;m. (3) OC1, OC2 and OC3 were the dominant OC fragments for all the tested ships, while EC1 and EC2 were the main EC fragment for ships running on heavy fuel oil (HFO) and marine diesel fuel, respectively; Different OC and EC fragments presented different distributions in different particle sizes. (4) Low power diesel fishing boats (LPDF) had much higher PAHs emission ratios than high power diesel vessels (HPDV) and heavy fuel oil vessel (HFOV) in fine particles, and HFOV had the lowest values. (5) PAHs and n-alkanes showed different profile patterns for different types of ships and also in different particle size bins, which meant that the particle size should be considered when source apportionment was conducted. It is also noteworthy from the results in this study that the smaller the particle size, the more toxic the particle was, especially for the fishing boats in China.</p>