2022
DOI: 10.1021/acsaem.2c01405
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Recent Advances in Cu-Based Metal–Organic Frameworks and Their Derivatives for Battery Applications

Abstract: Due to the increasingly serious energy consumption and demand worldwide, the development of advanced, flexible, and versatile advanced batteries and related materials has become an important research topic in the modern world. Copper-based metal–organic frameworks (Cu-MOFs) have large specific surface areas, high porosities, adjustable structures, simple preparation methods, and low cost. In recent years, the research on the chemical composition, structure, preparation methods, and application of Cu-MOFs and t… Show more

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Cited by 21 publications
(7 citation statements)
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“…As a biological/eco-friendly transition metal, Zn exists in a wide variety of MOFs including DMOF, CID and IRMOFs, as well as zeolitic imidazolate frameworks (ZIFs) . Cu-based MOFs usually comprise coordinated unsaturated sites provided by strong electrophilic copper atoms; particularly, many of them with a paddle wheel structure like HKUST-1 are commonly investigated . In addition, Ni-, Co-, and Mg-based MOF-74 exhibit the highest K H among all the metal types, owing to the large density of open metal sites.…”
Section: Resultsmentioning
confidence: 99%
See 1 more Smart Citation
“…As a biological/eco-friendly transition metal, Zn exists in a wide variety of MOFs including DMOF, CID and IRMOFs, as well as zeolitic imidazolate frameworks (ZIFs) . Cu-based MOFs usually comprise coordinated unsaturated sites provided by strong electrophilic copper atoms; particularly, many of them with a paddle wheel structure like HKUST-1 are commonly investigated . In addition, Ni-, Co-, and Mg-based MOF-74 exhibit the highest K H among all the metal types, owing to the large density of open metal sites.…”
Section: Resultsmentioning
confidence: 99%
“…9 Cu-based MOFs usually comprise coordinated unsaturated sites provided by strong electrophilic copper atoms; particularly, many of them with a paddle wheel structure like HKUST-1 are commonly investigated. 52 In addition, Ni-, Co-, and Mg-based MOF-74 exhibit the highest K H among all the metal types, owing to the large density of open metal sites. Crbased MOFs (Cr-soc-MOF-1, MIL-100, and MIL-101) have the highest q max , attributing to the strong Lewis acidity and low redox potential of Cr 3+ .…”
Section: Featurization Of Mofsmentioning
confidence: 99%
“…Cu-MOFs generally hold large specific surface areas and high porosities through simple and easily scaled-up preparation methods with low cost . In recent years, the exploration of the chemical composition, framework structure, synthesis approaches, and applications of Cu-MOFs has experienced continuous revolutions and developments, and many of them have gradually evolved into brilliant candidates for gas adsorption and separation. , Considering the numerous advantages mentioned above, the experimental Cu-MOF libraries along with 876 MOFs are delicately selected, which have a large pore size enough to accommodate CH 4 , covering an extensive range of structural and chemical characteristics. This library has also been successfully employed for large-scale screening of other systems, such as C 2 H 2 /CO 2 , H 2 /D 2 , and CO 2 /N 2 . …”
Section: Resultsmentioning
confidence: 99%
“…In addition, CD-MOFs were also used for sensing assays. Recently, Chen Y et al (2022) proposed a novel sensor for determinating luteolin (3′, 4′, 5, 7-tetrahydroxyflavonoids, LU) by preparing a glassy carbon electrode (MoO 3 -PEDOT/CD-MOF/GCE) using γ-CD-MOF, MoO 3 and a flexible conducting polymer poly (3,4-ethylenedioxythiophene) (PEDOT). The in situ growth of PEDOT on MoO 3 nanorods effectively improves the stability, dispersion, and electrical conduction efficiency of PEDOT.…”
Section: Application Of Mofs In Food Contamination Adsorption and Det...mentioning
confidence: 99%