Carbon
nanoframeworks have received considerable attention in electromagnetic
wave absorption (EWA), benefiting from their low mass density, cost
effectiveness, environmental friendliness, and strong mechanical strength.
Although various works have been performed to achieve carbon nanostructures
with favorable electromagnetic behavior, the mechanism behind the
application is still ambiguous, typically the effect of amorphous
and graphitic components on the EWA performances. Accordingly, we
modulate carbon nanotubes with a controllable amorphous–graphitic
ratio based on a facile carbonization strategy. With the increased
processing temperature, CNTs show increased graphitic formation simultaneously
with the removal of amorphous carbon. Meanwhile, the N-containing
groups are also converted from defective N toward graphitic N. The
optimum performance is achieved with a strong reflection loss (−61.25
dB) and broad bandwidth (6.24 GHz) at 700 °C. Simulation is further
applied to demonstrate the effects of CNTs with different amorphous–graphitic
ratios. Such work elucidates the impact mechanism of amorphous and
graphitic carbon on the electromagnetic behavior, resulting in the
scalable application of carbon materials.