Recent advances in flame retardant polymers via thiol-ene click chemistry

Çakmakçı, Emrah

doi:10.1080/10601325.2023.2280237

Journal of Macromolecular Science, Part A

2023

DOI: 10.1080/10601325.2023.2280237

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Recent advances in flame retardant polymers via thiol-ene click chemistry

Emrah Çakmakçı

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Cited by 7 publications

References 102 publications

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Phosphorus‐Containing Biobased Dimethacrylate Resin with Imine Linkages

Ozukanar,

Çakmakçi,

Kumbaraci

2024

Macro Materials & Eng

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There is a high demand for highly biobased photocurable coatings for a wide range of applications. In this work, a photocurable coating formulation is developed based on isobornyl acrylate (IBOA) and a biobased polyester diacrylate. Besides, a phosphorous‐containing biobased dimethacrylate resin having imine groups (VDDM) is synthesized. Different ratios of VDDM are added to the biobased base formulation. VDDM is characterized by nuclear magnetic resonance (NMR) and Fourier transform infrared (FTIR) spectroscopies. The formulations are coated on aluminum substrates and photocured under UV light. The biobased contents of the prepared networks are in the range of ≈68–79%. Coatings display a good adhesion on the aluminum substrates. The incorporation of VDDM into the formulations slightly increases the glass transition temperature values. Moreover, VDDM enhances the hydrophilicity of the coatings. VDDM‐free coatings are found to be resistant to degradation under basic and acidic media, but the presence of imine bonds in VDDM leads to the partial degradation of the prepared networks under acidic aqueous conditions. Finally, it is demonstrated that the coatings prepared herein are resistant to corrosion. The prepared highly biobased networks in this study have the potential to be used as photocurable coil coatings.

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Phosphorus‐Containing Biobased Dimethacrylate Resin with Imine Linkages

Ozukanar,

Çakmakçi,

Kumbaraci

2024

Macro Materials & Eng

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Biobased polysulfides prepared via inverse vulcanization with properties of intrinsic self-extinguishment and thermal remodeling

Li,

Zhang

et al. 2024

European Polymer Journal

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Cyclotriphosphazene-based crosslinked networks with tunable thermal, mechanical, and flame-retardant properties

Hu,

Zhang,

Weng

et al. 2025

Journal of the Taiwan Institute of Chemical Engineers

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Recent advances in flame retardant polymers via thiol-ene click chemistry

Cited by 7 publications

References 102 publications

Phosphorus‐Containing Biobased Dimethacrylate Resin with Imine Linkages

Phosphorus‐Containing Biobased Dimethacrylate Resin with Imine Linkages

Biobased polysulfides prepared via inverse vulcanization with properties of intrinsic self-extinguishment and thermal remodeling

Cyclotriphosphazene-based crosslinked networks with tunable thermal, mechanical, and flame-retardant properties

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