Recent advances in metal–organic frameworks–derived carbon-based materials in sulfate radical-based advanced oxidation processes for organic pollutant removal

Sulfate Radical-Based Degradation of Organic Pollutants: A Review on Application of Metal-Organic Frameworks as Catalysts

“…Third, biochar is a carbon-rich material that can act as a reducing agent, improving the MOFs’ stability . The reducing properties of biochar can help to mitigate this degradation and extend the MOFs’ lifespan Table provides a list of some organic pollutant degradation by activated PMS/PS by biochar-modified MOFs.…”

More effective peroxymonosulfate activation for tetracycline removal by Co–FeN/@BC assisted by micro-electrolysis: performance and mechanism

“…[17][18][19] Due to the exceptional characteristics of MOFs and the remarkable catalytic impact of transition metals in the activation of PMS, MOFs are frequently utilized as a precursor for preparation purposes. 20 A special structure (core and shell) with iron as the negative electrode and carbon as the positive electrode was prepared using Fe-MOF as the precursor, resulting in a tight short-circuit connection between the positive and negative electrodes of the galvanic cell system, 21 reduced erosion of Fe 0 during pollutant degradation due to the protection of the outer carbon layer, improved electron transfer efficiency and enhanced activation of PMS. 22 However, Fe-C IME is inefficient for practical applications.…”

Fabrication of two 2D Cu-based coordination polymers via a secondary ligand adjustment and a derived Cu/Cu2O heterojunction for an enhanced dye removal capacity

“…[11][12][13][14][15] As a kind of structurally controlled, long-range ordered material, recently researchers attempted the pyrolysis of CPs to obtain various metal (M) and/or metal oxide (MO) materials. 16,17 However, the oriented synthesis and specific composition of carbon-metal-metal oxide (C-M-MO) composites is still quite difficult. 18,19 In order to solve this problem, recently researchers attempted the pyrolysis/ thermolysis of Cu-CPs to obtain various Cu/CuO, CuO/Cu 2 O materials.…”