Superhydrophobic surfaces are renowned for their extreme
hydrophobicity
and versatility, showing great potential in numerous applications.
Yet, the complexity of their production and susceptibility to mechanical
and chemical degradation significantly limit their practical use.
Herein, we introduce a straightforward one-step, solvent-free method
for the in situ growth of polysilsesquioxane nanospikes (PNS) on glass
microfibers, creating a hierarchical micronano composite material
with excellent superhydrophobic properties, evidenced by a water contact
angle of approximately 170° and a rolling angle below 3°.
This composite exhibits exceptional stability against severe temperatures,
humidity, and corrosive substances, including strong acids/bases and
organic solvents, maintaining its superhydrophobicity even after repeated
mechanical abrasion and oil contamination. Such resilience is attributed
to the synergistic effect of its micronano hierarchical structure
and the three-dimensional, covalently cross-linked structure of the
PNS. Notably, it can easily and rapidly transform between superhydrophobic
and superhydrophilic states via simple plasma treatment and surface
re-engineering, facilitating its application in the highly efficient
(>98%) separation of diverse and complex oil–water mixtures.
This work opens promising avenues for applying superwettable surfaces
in practical scenarios, especially those demanding durability and
adaptability.