With an emphasis on remarkable properties, twisted vertical
heterostructures
have received particular attention in experimental and theoretical
works. They have promising unknown effects in science and technology.
These twisted systems can be considered a platform for the formation
of crystalline film structures. In this paper, we consider one of
them, diamond-like crystals with Moiré atomic structure formed
from twisted two-dimensional hexagonal layers. Analogues of carbon
Moiré diamanes are nanometer-thick films obtained by both stacking
and twisting near 30° of two functionalized monolayers of nitrides
(AlN, BN, GaN), which have already been actually obtained. We study
their energetically stable atomic configurations and electronic and
elastic properties. The proposed hydrogenated and/or fluorinated (second
side, Janus structures) Moiré nitridane nanostructures with
a twisted angle of 27.8° possess a wide band gap from 3 to 4
eV. Electronic band structures are characterized by many flattened
bands located near the edges of the valence and conduction bands,
which tend to be signatures of Moiré superlattices. The Moiré
nitridanes can be used as a base for two-dimensional semiconductors
with low-dispersive flattened bands and strong localization of the
electronic states, which should increase the probability of their
resonant IV characteristics and light excitations.
Thus, the circumstance is useful for nano- and optoelectronic resonant
devices. In addition, it was found that hydrogenated and fluorinated
Moiré nitridane and nitride films have some very different
elastic responses, which are attractive for mechanoelectric applications.