Recent advances in the electrochemical applications of Ni-based metal organic frameworks (Ni-MOFs) and their derivatives

Liu, Xuezhang; Yang, Hanping; Diao, Yingyao; He, Qi; Lu, Chengyu; Singh, Ayushi; Kumar, Abhinav; Liu, Jianqiang; Lei, Qian

doi:10.1016/j.chemosphere.2022.135729

Cited by 57 publications

(23 citation statements)

References 154 publications

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“…High porosity, high surface/volume ratio, and morphology caused NiO NPs to have suitable electrochemical sensing. Due to its extensive modulation range of electro‐chromic activity it acts as efficient electron mediator in electrochemical sensors based on the outstanding catalytic future of the Ni(II)/Ni(III) redox system [60–70] …”

Section: Introductionmentioning

confidence: 99%

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Electrochemical Quantification of Tyrosine in the Presence of Analogous Amino Acids

Amani-Beni

Nezamzadeh‐Ejhieh

2023

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Amnio acids are essential for body life, and thus, introducing novel simples/sensitive techniques/catalyst for detecting their low levels, especially in real samples and mixtures, is a great issue in analytical/bioanalytical chemistry. Thus, NiO nanoparticles were synthesized and used for the modification of a carbon paste electrode (CPE) for the square wave voltammetric (SqW) determination of tyrosine (Tyr) in the presence of tryptophan (Tryp), phenylalanine (PhA), and cysteine (Cis) amino acids (AA), all having the À CH 2 À CH(NH 2 )À COOH functional group. The calibration sensitivity was increased in interfering AA species which caused the decreased detection (for example, detection limit (DL) 1.32 μM to 0.88 μM Tyr) and quantification limits. For different concentrations of interfering AA species, the linear range (LR) was decreased that was more intense with an increase in AA amount. For example, the LR of 5-1800 μM Tyr in the absence of other AA species was changed to 80-800, 90-850, and 70 À 1000 μM Tyr in the presence of 20 mM Tyr, Csy, and PhA, respectively. A g-value of 0.487 < g 0.05,6,5 = 0.5875 confirmed the long-term stability of the electrode for 4 months. The electrode showed good selectivity towards Tyr in the presence of some amino acids and inorganic salts. Recovery experiments also confirmed the good capability of the electrode in Tyr quantification in a complex matrix such as six human serums used.

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Section: Introductionmentioning

confidence: 99%

“…Due to its extensive modulation range of electro-chromic activity it acts as efficient electron mediator in electrochemical sensors based on the outstanding catalytic future of the Ni(II)/Ni(III) redox system. [60][61][62][63][64][65][66][67][68][69][70]…”

Section: Introductionmentioning

confidence: 99%

Electrochemical Quantification of Tyrosine in the Presence of Analogous Amino Acids

Amani-Beni

Nezamzadeh‐Ejhieh

2023

ChemistrySelect

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“…[18,26] Furthermore, we have presented the activities of pure Ni-MOFs for comparison reasons without presenting details as the topic extensively reviewed in recently published works. [27,28] Thus the article gives brief accounts on recent developments of Ni-Co and Ni-Fe bimetallic MOFs with particular emphasis on 1) the synthesis strategies of Ni-based MOFs and the commonly used organic linkers, 2) application as OER and HER catalysts, and 3) prospects and future challenges.…”

Section: Introductionmentioning

confidence: 99%

Minireview: Ni–Fe and Ni–Co Metal–Organic Frameworks for Electrocatalytic Water‐Splitting Reactions

et al. 2022

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“…Thus, NiO NPs, as the electrochemical sensor, act as efficient electron mediators due to the unusual catalytic activity of the Ni(II)/Ni(III) redox system. Finally, NiO has been widely used for constructing fuel and solar cells (dye-sensitized solar cells), gas sensors, electrochemical sensors, adsorbents, supercapacitor materials, anodic materials in Li-ion batteries, transparent electrodes, photocatalyst, etc.. [55][56][57][58][59][60][61][62][63] Optimization is a method in which the highest overall process efficiency could be achieved with no increase in the cost by choosing the best elements from sets of influencing alternatives, called independent variables) On the other hand, the best characteristics and performances can be reached under optimized conditions. Two well-known optimization methods are OFAT and DOE methods.…”

Section: Introductionmentioning

confidence: 99%

“…Finally, NiO has been widely used for constructing fuel and solar cells (dye‐sensitized solar cells), gas sensors, electrochemical sensors, adsorbents, supercapacitor materials, anodic materials in Li‐ion batteries, transparent electrodes, photocatalyst, etc. [55–63] …”

Section: Introductionmentioning

confidence: 99%

The Experimental Design Approach in Square‐Wave Voltammetric Determination of Tamoxifen by NiO‐CPE**

Raeisi‐Kheirabadi

Nezamzadeh‐Ejhieh

2022

ChemistrySelect

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Due to the explosive global increase of various cancers, the need to introduce/develop novel catalysts/sensors for quantitative determination of cancer drugs is emphasized. Nickel oxide nanoparticles (NiO‐NPs) calcined at 200 °C were used as a modifier of carbon paste electrode (CPE) to quantify tamoxifen (TAM) in an aqueous solution. The square wave voltammetry (SqW) was used due to its high sensitivity. The modified NiO‐CPE showed an SqW anodic peak current with a peak potential of about 420 mV in the NaOH‐supporting electrolyte. This peak current was decreased when TAM analyte was added to the test solution. Thus, this reduced peak current (Δi) was used to quantify TAM in solution. The experimental design used the response surface methodology (RSM) approach to study the simultaneous interaction effects between the influencing variables. The optimized run was associated with a 10 % NiO ingredient in the CPE, 0.3 M NaOH, an amplitude of 200 mV, a step potential of 3 mV, and a frequency of 25 Hz. A proportional behavior was obtained between the mentioned Δi and TAM concentration in the range of 10–60 nM. The detection (LOD) and quantification (LOQ) limits were 1.81±0.35 and 6.05±0.24 nM, respectively. Interfering and recovery results confirmed the applicability of the proposed NiO‐CPE electrode for TAM determination in complex matrixes and the direct assay of the drug in human serum.

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Recent advances in the electrochemical applications of Ni-based metal organic frameworks (Ni-MOFs) and their derivatives

Cited by 57 publications

References 154 publications

Electrochemical Quantification of Tyrosine in the Presence of Analogous Amino Acids

Electrochemical Quantification of Tyrosine in the Presence of Analogous Amino Acids

Minireview: Ni–Fe and Ni–Co Metal–Organic Frameworks for Electrocatalytic Water‐Splitting Reactions

The Experimental Design Approach in Square‐Wave Voltammetric Determination of Tamoxifen by NiO‐CPE**

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