Recent advances in the practical use of the redox properties of manganese porphyrins

Ломова, Т. Н.; Tsaplev, Yu. B.; Klyueva, M. E.; Овченкова, Е. Н.

doi:10.1016/j.jorganchem.2021.121880

Cited by 10 publications

(1 citation statement)

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“…Most typical complexing ions form stable porphyrin complexes, the oxidation state in which can change from +1 to +6. [1][2][3] The rate constant of the metal porphyrins (MPs) dissociation into a metal cation and a porphyrin ligand was recognized as the best characteristic of the MP stability beginning from the first works in the topic to the recent ones [4][5][6][7][8][9] due to irreversibility of the MP formation and dissociation reactions. According to this frame of reference, main group porphyrin complexes should be attributed to the most stable MPs despite the fact that the 13, 14, 15 group p-elements are located in the Periodic Table between the ionic and covalent compounds that the elements form.…”

Section: Introductionmentioning

confidence: 99%

The p-Metal Porphyrins: from Specificity of Properties to Application in Medicine, Catalysis, and Optoelectronics

Ломова¹

2021

MHC

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The article is the short review of the recent works in the physical and applied chemistry of the main group porphyrin complexes. Several classic articles on the topic are included in the discussion. Special attention is paid to the specificity of preparation methods, with the demonstration of the specific original syntheses, as well as of optical properties, reactivity and new applications. The prospects of the main group porphyrin complexes in medicine, catalysis, and optoelectronics are briefly presented.

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