Recent advances of metal phosphates-based electrodes for high-performance metal ion batteries

Emerging two-dimensional nanostructured manganese-based materials for electrochemical energy storage: recent advances, mechanisms, challenges, and prospects

“…Because of saving time, simple operating procedures, low cost, and easy control of preparation conditions (can be carried out even at room temperature), it is widely used to synthesize 2D nanostructured Mn-based materials. 88 Dang et al synthesized MnO 2 ultrathin nanosheets via a simple method in which KMnO 4 was dissolved in 50 mL deionized water, and then carbon nanospheres were added and heated to 70 C. 89 Adopting a one-step enhanced chemical bath deposition (ECBD) method at a low temperature ($50 C), size-and thicknesscontrollable MnO 2 nanosheets were fabricated. Meanwhile, BrO 3…”

Microwave-assisted rapid synthesis of titanium phosphate free phosphorus doped Ti3C2 MXene with boosted pseudocapacitance

“…Compact and aggregated phosphate structures without having open channels prevent easy ion intercalation and generate a low surface area with a poor level of porosity, which limits the electrolytic accessibility and nally leads to low energy storage performance. 38,39 So, we believe that the presence of such electrochemically inferior compact titanium phosphates in the P doped Ti 3 C 2 T x MXene system has dual disadvantages like (a) it increases the mass or the volume of the electrode without contributing much to its total charge storage, and (b) it also blocks the open channels available among the layers of MXene to restrict the ion intercalation, and hence, limit the energy storage performance further. So, it is essential to restrict the formation of electrochemically inferior compact titanium phosphates during P doping in Ti 3 C 2 T x , but this still remains a challenge and unaddressed.…”

Zn3V4(PO4)6: A New Rocking-Chair-Type Cathode Material with High Specific Capacity Derived from Zn2+/H+ Cointercalation for Aqueous Zn-Ion Batteries

“…Recently, phosphates compounds have been widely used in aqueous and nonaqueous alkali metal-ion batteries because of their stable structure and high operating voltage. − However, only a few of vanadium-based phosphates have been reported as cathodes for AZIBs. ,− The multivalent transition metal ions V 5+/4+/3+ can undergo multielectron reactions and be favorable to increase the specific capacity. In addition, the induction effect of the PO 4 3– group increases the redox potential.…”