Recent advances on electrochemical methods in fabricating two‐dimensional organic‐ligand‐containing frameworks

Abstract

Organic‐ligand‐containing frameworks have drawn considerable attention due to their multifunctional properties as well as tunable structures for broad applications. Among numerous synthesis methods developed in the past two decades, electrochemical processing has been demonstrated as one of the most efficient, safe, and facile ways to realize the large‐scale and highly controllable production of organic‐ligand‐containing frameworks. In this review, the progress of electrochemically induced crystallization and thin film fabrication of organic‐ligand‐containing frameworks is summarized in a well‐rounded way. Besides, the mechanism and processing parameters are also discussed. Moreover, the main challenges are also expounded for providing some guidance on the future development of organic‐ligand‐containing frameworks, especially for covalent‐organic frameworks and hydrogen‐bonded organic frameworks.

Process of metal–organic framework (MOF)/covalent–organic framework (COF) hybrids-based derivatives and their applications on energy transfer and storage

“…Recently, COFs constructed using rigid aromatic molecules as building blocks 144 have often been applied as precursors or templates for the construction of efficient electrocatalysts due to the virtues of their diverse synthesis methods, low density, high surface area, high thermal and chemical stability, and easy functionalization. 145 Employing COFs as precursors can facilitate better control over the N dopant density, thus generating more kinds of N species.…”

Multicomponent Electrocatalytic Selective Approach to Unsymmetrical Spiro[furo[3,2-c]pyran-2,5′-pyrimidine] Scaffold under a Column Chromatography-Free Protocol at Room Temperature

“…All melting points were measured with a Stuart SMP30 melting-point apparatus (Stuart Equipment, Cole-Parmer, UK) and were uncorrected. 1 H and 13 C-NMR spectra were recorded in CDCl 3 with Bruker AM300 spectrometer (Bruker Corporation, Billerica, MA, USA) at ambient temperature. Chemical shift values are relative to Me 4 Si.…”

“…Chemistry 2022, 4 Organic electrosynthesis has emerged in recent decades as a part of modern organic synthesis, which has set the stage for innovative chemical processes using novel mechanistic pathways [10][11][12][13]. Nevertheless, the use of electrochemical methods is still limited by equipment and procedure complexity, as well as long reaction time.…”

An overview of supercapacitors electrode materials based on metal organic frameworks and future perspectives

“…Core-shell nanorods of ZnO@Ni 3 S 2 prepared by Xing et al via electrodeposition method exhibit high specific capacitance and maintain 42% of original capacitance even after 2000 cycles. [79][80][81][82]…”