Recent Advances on Stereoselective Organocatalytic Reactions. Organocatalytic Synthesis of Natural Products and Drugs

Raj, Monika; Singh, Vinod K.

doi:10.1002/9781118087992.ch11

Catalytic Methods in Asymmetric Synthesis 2011

DOI: 10.1002/9781118087992.ch11

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Recent Advances on Stereoselective Organocatalytic Reactions. Organocatalytic Synthesis of Natural Products and Drugs

Monika Raj

Vinod K. Singh

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2012

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Sequential Suzuki/Asymmetric Aldol and Suzuki/Knoevenagel Reactions Under Aqueous Conditions

et al. 2012

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Here we describe for the first time a sequential Suzuki/asymmetric aldol reaction. Such sequential approach was achieved through the combined use of an ionic liquid supported palladium catalyst and the organocatalyst trans-4-(2,2-diphenylacetoxy)proline. Suzuki and asymmetric aldol reactions were performed under aqueous conditions. The use of a palladium catalyst under basic conditions allowed also the first example of sequential Suzuki/Knoevenagel reaction.\ud Reactions were carried out under aqueous conditions and products were isolated in good to high yields and, in the case of the Suzuki/aldol reaction, with diastereoselectivities up to 91:9 and enantioselectivities up to at least 99%

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Sequential Suzuki/Asymmetric Aldol and Suzuki/Knoevenagel Reactions Under Aqueous Conditions

et al. 2012

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Recent Advances on Stereoselective Organocatalytic Reactions. Organocatalytic Synthesis of Natural Products and Drugs

Cited by 1 publication

References 376 publications

Sequential Suzuki/Asymmetric Aldol and Suzuki/Knoevenagel Reactions Under Aqueous Conditions

Sequential Suzuki/Asymmetric Aldol and Suzuki/Knoevenagel Reactions Under Aqueous Conditions

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