2020
DOI: 10.1055/s-0040-1705966
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Recent Developments in Heck-Type Reaction of Unactivated Alkenes and Alkyl Electrophiles

Abstract: The Mizoroki–Heck reaction is considered as one of the most ingenious and widely used methods for constructing C–C bonds. This reaction mainly focuses on activated olefins (styrenes, acrylates, or vinyl ethers) and aryl/vinyl (pseudo) halides. In comparison, the studies on unactivated alkenes and alkyl electrophiles are far less due to the low reactivity, poor selectivity, as well as competitive β-H elimination. In the past years, a growing interest has thus been devoted and significant breakthroughs have been… Show more

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Cited by 25 publications
(1 citation statement)
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“…The widespread applications of styrenes as readily available and nonactivated aromatic terminal olefins in important reactions such as Heck reaction, olefin hydroformylation, Wacker process, olefin metathesis, and synthesis of alkylthio-substituted 1,4-enediones demonstrate their importance in synthetic organic chemistry.…”
Section: Introductionmentioning
confidence: 99%
“…The widespread applications of styrenes as readily available and nonactivated aromatic terminal olefins in important reactions such as Heck reaction, olefin hydroformylation, Wacker process, olefin metathesis, and synthesis of alkylthio-substituted 1,4-enediones demonstrate their importance in synthetic organic chemistry.…”
Section: Introductionmentioning
confidence: 99%