“…The Q phase is a key phase in Al alloys, including not only 6xxx series Cu-added Al-Mg-Si alloys [ 7 ], but also 4xxx series Cu-added Al-Si-Mg alloys [ 8 , 9 ] and 2xxx series Si-added Al-Cu-Mg alloys [ 10 ], existing as as-cast constituents [ 8 , 10 ] and nano-precipitates [ 9 , 11 ]. Abundant research has been conducted to clarify the precipitation behaviors of Al-Mg-Si(-Cu) alloys during age hardening, especially paint bake hardening, a typical heat treatment process for auto body panels [ 5 ], thus guiding the design of new generations of alloys. In these alloys, Cu additions have been found to induce the formation of Cu-containing nano-precipitates, such as Q [ 2 , 12 , 13 , 14 ] in the over-aged state, its precursor Q′ [ 7 , 15 , 16 , 17 , 18 ], C, S, L, QP [ 19 ], and QC [ 20 , 21 ], as well as β″-Al 2 Mg 5 Si 4 [ 22 ] with Cu substitutions [ 23 ] in the peak-aged state; meanwhile, the alloys are hardened to higher levels compared to Cu-free alloys with the same Mg and Si contents [ 12 ].…”