Recent Developments in the Conversion of Synthesis Gas to Short‐Chain Alcohols over Cu‐Co‐Based Catalysts

Schmidt, Stefan; Göbel, Christoph; Nebel, Janine; Wiesmann, Thomas; Hamel, Christian; Reinsdorf, Arne; Wolf, Dorit; Gehrmann, Stefan; Tenhumberg, Nils; Kaluza, Stefan

doi:10.1002/cite.201800023

Cited by 14 publications

(11 citation statements)

References 79 publications

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“…the overall concept with steel mill, gas pipes for steel mill process gases, water electrolysis, units for gas cleaning and conditioning as well as the technical center with a test facility for the production of C2‐C4 alcohols is shown. In this project carbon‐cobalt‐copper catalysts are used , . A successful scale‐up of this CCU approach can help to increase the sustainability of the steel mill, but also of alcohol production.…”

Section: Sustainable Production Pathways To C2‐c4 Alcoholssupporting

confidence: 85%

Production and Use of Sustainable C2‐C4 Alcohols – An Industrial Perspective

Gehrmann

Tenhumberg

2020

Chemie Ingenieur Technik

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In the recent past, society has become increasingly aware of the environmental impact of political and corporate action. Hence, several industrial sectors are currently undergoing a transition to more sustainable products and processes. Sustainable production processes for C2‐C4 alcohols can help to decrease the environmental impacts of large downstream markets such as fuels and polymers. However, a reliable and consistent framework is needed for companies to further develop and commercialize these processes. Furthermore, standardized procedures for determining the sustainability of a process are essential in evaluating the environmental benefits.

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Section: Sustainable Production Pathways To C2‐c4 Alcoholssupporting

confidence: 85%

Production and Use of Sustainable C2‐C4 Alcohols – An Industrial Perspective

Gehrmann

Tenhumberg

2020

Chemie Ingenieur Technik

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“…It is questionable whether the functionality of copper in the electroreduction of CO 2 can be further clarified if another element, [111] such as Co[ 66b , 66c , 66e ] or Ni, is added to the copper‐based catalyst because they change the reactivity in a complex way. The chemistry of the support is likewise critical.…”

Section: Copper As a Catalystmentioning

confidence: 99%

Chemical Batteries with CO₂

Schlögl

2021

Angew Chem Int Ed

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Efforts to obtain raw materials from CO 2 by catalytic reduction as a means of combating greenhouse gas emissions are pushing the boundaries of the chemical industry. The dimensions of modern energy regimes, on the one hand, and the necessary transport and trade of globally produced renewable energy, on the other, will require the use of chemical batteries in conjunction with the local production of renewable electricity. The synthesis of methanol is an important option for chemical batteries and will, for that reason, be described here in detail. It is also shown that the necessary, robust, and fundamental understanding of processes and the material science of catalysts for the hydrogenation of CO 2 does not yet exist.

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“…28,29 In addition, additives such as alkali metal promoters and supports have a great inuence on the activity and selectivity of such catalysts. 30 Cu-Co catalysts must have alkali metals, otherwise the selectivity of alcohols will be very low. The role of the carrier is also obvious.…”

Section: Modied F-t Catalystmentioning

confidence: 99%