Recent Developments in the Experimental Determination of Thermodynamic Quantities of Metals and Alloys

Komarek, K. L.

doi:10.1002/bbpc.19830870902

Cited by 28 publications

(3 citation statements)

References 104 publications

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“…Experimental details are given in e.g. [3,6]. Results obtained as a function of temperature at a constant composition from e.m.f.…”

Section: Heat Capacitymentioning

confidence: 99%

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Thermodynamics of liquid alloys

Sommer¹

2007

Journal of Non-Crystalline Solids

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“…Experimental details are given in e.g. [3,6]. Results obtained as a function of temperature at a constant composition from e.m.f.…”

Section: Heat Capacitymentioning

confidence: 99%

“…[1][2][3][4][5][6][7][8][9][10]. Calorimetric measurements to determine the enthalpy of formation and the heat capacity of liquid alloys are discussed in Section 2.…”

Section: Introductionmentioning

confidence: 99%

Thermodynamics of liquid alloys

Sommer¹

2007

Journal of Non-Crystalline Solids

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“…Since my field is thermodynamics of inorganic metallic systems and thermodynamics does depend on the establishment of equilibrium, experimental techniques used for such measurements will -roughly speaking -be confined to the temperature regimen above 1000 K. In previous publications the author has quite extensively discussed experimental techniques applied in high temperature thermodynamics and phase diagram studies (Ref. [1][2][3][4][5]. Since then other general (e. g. Ref.…”

Section: Introductionmentioning

confidence: 99%

Experimental techniques in high temperature thermodynamics

Komarek¹

1992

Pure and Applied Chemistry

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-An overview of the most recent developments of experimental techniques used in high temperature thermodynamics will be given. Calorimetric, EMF, and vapor pressure methods will be discussed with special emphasis on solid electrolyte galvanic cell techniques and Knudsen effusion mass spectrometry.The essential criteria for the satisfactory application of solid electrolyte galvanic cell methods will be presented and the principal electrolytes presently in use will be surveyed. Special variations of the cell technique used in thermodynamic studies are described.With respect to vapor pressure methods the focus will be on the fundamentals of the Knudesen effusion mass spectrometry, Recent methodic developments were less due to radically new techniques but more to automated control, data acquisition and processing.

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Vapor pressure methods: A source of experimental thermodynamic data

Ipser

1998

Ber Bunsenges Phys Chem

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An overview is given of the vapor pressure methods which are used for the determination of partial thermodynamic quantities. The methods are divided into four groups: static methods (pressure gauges, atomic absorption, and others); dynamic methods (boiling point method, transpiration method); effusion methods (Langmuir method, different variants of the Knudsen method); equilibration methods (equilibration with gas mixtures, isopiestic method, dew point method). The characteristics of each group are discussed shortly, and some examples of application are given from the recent literature.

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Recent Developments in the Experimental Determination of Thermodynamic Quantities of Metals and Alloys

Cited by 28 publications

References 104 publications

Thermodynamics of liquid alloys

Thermodynamics of liquid alloys

Experimental techniques in high temperature thermodynamics

Vapor pressure methods: A source of experimental thermodynamic data

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