Recent developments in the synthesis of N-aryl sulfonamides

Wu, Huizhen; Chen, Xuesong; Sun, Na-Bo; Sanchez-Mendoza, Alberto

doi:10.1080/00397911.2021.1936060

Cited by 12 publications

(9 citation statements)

References 72 publications

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“…They also possess a wide spectrum of biological activity. Palladium based catalysts are used for the synthesis of N ‐aryl sulfonamides, however, most significant disadvantage is their toxicity and high cost [104] . In an effort to develop environment‐friendly and cost‐effective catalyst, Nasrollahzadeh et al [105] .…”

Section: Guanylguanidines As Catalystmentioning

confidence: 99%

“…Palladium based catalysts are used for the synthesis of N-aryl sulfonamides, however, most significant disadvantage is their toxicity and high cost. [104] In an effort to develop environment-friendly and cost-effective catalyst, Nasrollahzadeh et al [105] immobilized copper(II) on metformin-functionalized chitosan coated Fe 3 O 4 magnetic nanoparticles. This heterogenous, magnetically separable copper nanocatalyst, Fe 3 O 4 -CS@Met-Cu(II) (C38, Figure 10i) was evaluated for its catalytic efficiency for N-arylation of 1°sulfonamides.…”

Section: N-arylation Of Primary Sulfonamidesmentioning

confidence: 99%

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Guanylguanidines: Catalyst and Ligand for Organic Transformations

Bankar¹,

Kathuria

2022

ChemistrySelect

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Guanylguanidines are well known for their wide range of therapeutic applications such as antidiabetic, anticancer, antifilarial, antitrypanosomal, antiaging, etc. Apart from this, they have been explored in the field of crystal engineering, organic synthesis as substrate, non‐linear optics etc. Their metal complexation ability and superbasic nature has paved their way in the field of organocatalysis. In the recent past, various guanylguanidine derivatives have been synthesized and have proven to be excellent catalysts in several organic reactions which include transesterification, C−C and C−N coupling, oxidation, reduction, Beckmann rearrangement etc. However, the limited studies call for more focused research in this direction to fasten the process of development of environmental‐friendly methods. In this review, a comprehensive and systematic discussion of guanylguanidine based catalysts and their applications in various organotransformations has been compiled and discussed meticulously. This review aims to highlight guanylguanidine moiety as a potential catalyst that can be utilized for design and development of novel guanylguanidine based catalysts.

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Section: Guanylguanidines As Catalystmentioning

confidence: 99%

Section: N-arylation Of Primary Sulfonamidesmentioning

confidence: 99%

Guanylguanidines: Catalyst and Ligand for Organic Transformations

Bankar¹,

Kathuria

2022

ChemistrySelect

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“…1 Furthermore, the pharmaceutical industry's increasing interest in clinical drugs containing N-heterocyclic compounds has further fueled research in this field. 2 There are two primary methods for forming C–N bonds using transition metal catalysts: cross-coupling reactions and C–H amination. Cross-coupling reactions involve the use of a Pd-catalyst to couple aryl- or alkenyl (pseudo)halides with amines, typically under specific catalytic conditions.…”

Section: Introductionmentioning

confidence: 99%

Recent advances in metal directed C–H amidation/amination using sulfonyl azides and phosphoryl azides

Krishna Rao,

Kareem,

Vali

et al. 2023

Org. Biomol. Chem.

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“…mentioned arylation of sulfonamides on their review article “Applications of palladium‐catalyzed C−N cross‐coupling reactions” [20] . Moreover, Sanchez‐Mendoza and co‐workers also reported a summary on “Recent developments in the synthesis of N ‐aryl sulfonamides” in 2021 [21] . However, the first two reviews are outdated and offered very limited information on our proposed topic.…”

Section: Introductionmentioning

confidence: 99%

“…[20] Moreover, Sanchez-Mendoza and co-workers also reported a summary on "Recent developments in the synthesis of N-aryl sulfonamides" in 2021. [21] However, the first two reviews are outdated and offered very limited information on our proposed topic. Similarly, the third review mainly focused on N-arylation of sulfonamides.…”

Section: Introductionmentioning

confidence: 99%

N‐Heteroarylation of Sulfonamides: An Overview

2023

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<i>N</i>‐Heteroaryl sulfonamides are an extremely significant variety of organosulfur compounds that are present in many significant FDA‐approved drugs and therapeutic agents. Therefore, synthesis of these N‐heteroaryl sulfonamides is one of most interesting topics among the synthetic organic chemists. Among the various synthetic methodologies, direct C–N bond formation through <i>N</i>‐heteroarylation of sulfonamides has emerged as a procedure continued of choice as it bypasses the genotoxicity common in the traditional methods. This review encompasses and summarizes the progress and development in this subject with literature coverage up to June 2023.

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Recent developments in the synthesis of N-aryl sulfonamides

Cited by 12 publications

References 72 publications

Guanylguanidines: Catalyst and Ligand for Organic Transformations

Guanylguanidines: Catalyst and Ligand for Organic Transformations

Recent advances in metal directed C–H amidation/amination using sulfonyl azides and phosphoryl azides

N‐Heteroarylation of Sulfonamides: An Overview

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