Recent progress and multifunctional applications of 3D printed graphene nanocomposites

Ponnamma, Deepalekshmi; Yin, Yifei; Salim, Nisa V.; Parameswaranpillai, Jyotishkumar; Thomas, Sabu; Hameed, Nishar

doi:10.1016/j.compositesb.2020.108493

Cited by 116 publications

(52 citation statements)

References 136 publications

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“…The principles and materials used in these processes are different. However, the suiTable 3D printing method for conductive carbon materials mainly includes FDM [ 53 , 54 ], SLS [ 55 , 56 ], SLA [ 57 ], and so on. The choice of 3D printing method depends on the application fields and the processing restrictions of the products, such as the concentration conditions of printing materials, and the properties of loaded fillers, etc.…”

Section: 3d Printing Of Conductive Carbon Materialsmentioning

confidence: 99%

A Review of Conductive Carbon Materials for 3D Printing: Materials, Technologies, Properties, and Applications

et al. 2021

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Carbon material is widely used and has good electrical and thermal conductivity. It is often used as a filler to endow insulating polymer with electrical and thermal conductivity. Three-dimensional printing technology is an advance in modeling and manufacturing technology. From the forming principle, it offers a new production principle of layered manufacturing and layer by layer stacking formation, which fundamentally simplifies the production process and makes large-scale personalized production possible. Conductive carbon materials combined with 3D printing technology have a variety of potential applications, such as multi-shape sensors, wearable devices, supercapacitors, and so on. In this review, carbon black, carbon nanotubes, carbon fiber, graphene, and other common conductive carbon materials are briefly introduced. The working principle, advantages and disadvantages of common 3D printing technology are reviewed. The research situation of 3D printable conductive carbon materials in recent years is further summarized, and the performance characteristics and application prospects of these conductive carbon materials are also discussed. Finally, the potential applications of 3D printable conductive carbon materials are concluded, and the future development direction of 3D printable conductive carbon materials has also been prospected.

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Section: 3d Printing Of Conductive Carbon Materialsmentioning

confidence: 99%

A Review of Conductive Carbon Materials for 3D Printing: Materials, Technologies, Properties, and Applications

et al. 2021

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“…Extrusion-based 3D printing is an additive manufacturing technology that offers the possibility to rapidly fabricate (i.e., hours) complex self-supporting three dimensional architectures with tuneable mechanical properties at low cost, with high precision (i.e., resolution: 50 -200 μm) and close to zero waste. 47,92,93 This technique employs a X,Y,Z-motion nozzle or stage to assemble 3D structures by extruding a continuous ink filament at room Please do not adjust margins Please do not adjust margins temperature in a layer-by-layer fashion, upon computerised control. [94][95][96] The viscoelastic ink materials (i.e., viscosity: 5 -500 000 mPa s; 2D material loading: 12-40 w% rapid drying time; selfsupporting) must present a shear thinning behaviour to facilitate the extrusion process, and enable shape retention after deposition.…”

Section: Extrusion-based 3d Printingmentioning

confidence: 99%

“…47,92,93 This technique employs a X,Y,Z-motion nozzle or stage to assemble 3D structures by extruding a continuous ink filament at room Please do not adjust margins Please do not adjust margins temperature in a layer-by-layer fashion, upon computerised control. [94][95][96] The viscoelastic ink materials (i.e., viscosity: 5 -500 000 mPa s; 2D material loading: 12-40 w% rapid drying time; selfsupporting) must present a shear thinning behaviour to facilitate the extrusion process, and enable shape retention after deposition. 97,98 By careful design, printed 3D macrostructures of 2DMs can present enhanced mechanical properties, such as high stretchability and negative Poisson's ratio in the case of graphene, 99,100 while retaining the inherent properties of the monolayers (e.g., high electrical/thermal conductivity, surface area, mechanical properties, etc.).…”

Section: Extrusion-based 3d Printingmentioning

confidence: 99%

2D material hybrid heterostructures: achievements and challenges towards high throughput fabrication

Maggini

Ferreira

2021

J. Mater. Chem. C

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“…The exceptional properties are not only constrained to graphene, but it is also transformed into derivative compounds such as graphene oxide and, reduced graphene oxide, etc. [ 3 , 4 , 5 ]. Graphene has the potential to gain thermal stability and can offer a large surface area with excellent mechanical strength to the matrix.…”

Section: Introductionmentioning

confidence: 99%

Influence of Graphene Oxide Contents on Mechanical Behavior of Polyurethane Composites Fabricated with Different Diisocyanates

et al. 2021

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The exceptional behavior of graphene has not yet been entirely implicit in the polymer matrix. To explore this fact in the present work, two series of Polyurethan (PU) composites were synthesized. The structural modification was observed by the use of two different diisocyanate of methylene diisocyanate (MDI) and hexamethylene diisocyanate (HMDI) in hydroxylterminated polybutadiene (HTPB) by using I,4 Butane diol (BD) as the chain extender. The variation in hard segment up to 25 (wt.%) in both series led to significant changes in the mechanical behavior of graphene oxide (GO) induced composites. Both series were prepared by an in situ polymerization process. Fourier transform infrared (FTIR) analysis showed a peak in the region of 1700 cm−1, which confirmed the conversion of the NCO group into urethane linkages. Thermal gravimetric analysis (TGA) revealed a thermal stability up to 450 °C @ 90% weight loss. The swelling behavior showed the optimum uptake of 30% of water and 40% of dimethyl sulfoxide (DMSO) with aliphatic diisocyanate. The values of storage modulus (E′), complex modulus (E*), and compliance complex (D*) were observed up to 7 MPa, 8 Mpa, and 0.7 MPa−1, respectively. The degree of entanglement (N) values were calculated from DMA and were found in the range of 1.7 × 10−4 (mol/m3). Phase segregation of PU was observed by scanning electron microscopy (SEM), elucidating the morphology of composites.

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Recent progress and multifunctional applications of 3D printed graphene nanocomposites

Cited by 116 publications

References 136 publications

A Review of Conductive Carbon Materials for 3D Printing: Materials, Technologies, Properties, and Applications

A Review of Conductive Carbon Materials for 3D Printing: Materials, Technologies, Properties, and Applications

2D material hybrid heterostructures: achievements and challenges towards high throughput fabrication

Influence of Graphene Oxide Contents on Mechanical Behavior of Polyurethane Composites Fabricated with Different Diisocyanates

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