Recent Progress in C—C Cross-Coupling Reaction of Pyridine<i>N</i>-Oxides

刘雅莉,; 张韻慧,; 费红艳,; 晋兴华,

doi:10.6023/cjoc201205020

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近些年重氮化合物特别是具有羰基结构的重氮化合物以一种新型的方式参与到过渡金属催化的1

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Cited by 4 publications

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“…氮-氧官能团的引入给喹啉的 C-H 活化反应带来了生机, 通过氮-氧导向的 C(2)位 C-H 官能化反应可以合成各种 2-取代的喹啉化合物. 但是, 喹啉 C(8)位的 C-H 键官能化反应的研究较少, 也存在着一定挑战 [23] . 2014 年, Chang 小组 [24] [26] .…”

Section: 近些年重氮化合物特别是具有羰基结构的重氮化合物以一种新型的方式参与到过渡金属催化的unclassified

Progress in Diazo Compounds Mediated Transition-Metal-Catalyzed C—H Alkylation

Wang¹,

Li²,

Wan³

et al. 2016

Chin. J. Org. Chem.

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Diazo compounds had been widely employed as a class of environment friendly and highly efficient coupling reagents in transition-metal-catalyzed C-H bonds insertion reactions. Recently, C-H alkylation of various arenes and heteroarenes has been achieved enormous successes using diazo compounds as the alkylation reagents under a new catalytic model. The recent progress in diazo compounds mediated transition-metal-catalyzed C-H alkylation and tandem C-H alkylation/cyclization is reviewed, including reaction mechanism and synthetic applications. Furthermore, the prospects of this reaction are also discussed.

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Section: 近些年重氮化合物特别是具有羰基结构的重氮化合物以一种新型的方式参与到过渡金属催化的unclassified