“…1 Various NLO materials, such as perovskites, 2–4 metal–organic frameworks, 5,6 metal oxides, 7,8 and two-dimensional materials, 9,10 have been explored for NLO devices. Among these, perovskites show the advantages of high light absorption, 11 extremely effective luminescence, 12 and prolonged carrier diffusion lengths, 13 making them ideal candidates for high performance optoelectronic devices, such as photodetectors, 14,15 lasers, 16,17 solar cells, 18,19 all-optical switches 20 and optical limiters. 21,22 Hybrid organic–inorganic metal halide perovskites, denoted as MAPbX 3 (MA = CH 3 NH 3 , X = Br, Cl, I), have demonstrated excellent NLO properties.…”