Single-photon creation through parametric downconversion underpins quantum technology for quantum sensing and imaging. Here we numerically study the creation of single photons in the near-and mid-infrared regime from 1.5-12 µm in a range of novel nonlinear semiconductor and chalcopyrite materials. We identify phase-matching conditions and single out regimes in which group-velocity matching can be achieved with commercially available pump lasers. Finally, we discuss how mid-infrared single photons can be detected. Using our numerical results, we identify materials and pump lasers for up-conversion detection in conventional wavelength bands. Our study provides a complete recipe for mid-IR single-photon generation and detection, opening up quantum enhancements for mid-IR applications such as bio-medical imaging, communication, and remote sensing.
INTRODUCTIONSingle-photon creation with quantum emitters or through parametric downconversion is a mature quantum technology with bright photon sources now routinely available at visible and telecommunications wavelengths. A major application area for single-photon sources is in quantum sensing and metrology, where they can exceed noise limitations intrinsic to classical systems for e.g. sub-shot-noise phase estimation [1] or absorption measurements in the few-photon regime [2].Expanding single-photon technology beyond the near-infrared (1 to 2 µm) into the midinfrared spectrum (2 to 20 µm) could enable quantum advantages for a host of mid-IR applications [3], e.g. medical imaging [4,5] at ultra-low light levels. It would further open up access to scatter-free atmospheric windows [6-8] for free-space quantum communication, and for quantum remote sensing, e.g. the detection of biological or chemical samples in the few-photon regime, stealth range finding, and in particular quantum LIDAR [9,10].The most popular method for generating single-photon pairs is parametric downconversion in crystals such as BBO, BiBO, PPLN and PPKTP. Due to their optical properties, they allow access from ultraviolet to near-infrared wavelengths. PPLN and PPKTP are suitable for generation of photons up to 5 µm, and single-photon generation and upconversion detection in PPLN has been demonstrated for up to 4 µm [11,12]. However, beyond that limit these two materials become opaque. A suite of novel nonlinear materials has recently been explored using widely tunable optical parametric oscillators (OPOs). Four of the most exciting materials are OPGaP, OPGaAs, CSP and ZGP, each of which exhibit transparencies that extend well beyond 5 µm.Here we numerically study mid-infrared photon generation in these materials, benchmarking against known results in PPLN and PPKTP. We show that wavelengths up to 13 µm can comfortably reached with available pump lasers. We identify parameter regimes for type-0, type-I and type-II phase-matching and highlight a number of special cases for which group-velocity matching between the pump and signal/idler photons can be achieved, allowing for the creation of spectrally pure s...