Recent progress in Prussian blue electrode for electrochromic devices

Zhang, Yongting; Li, Wanzhong; Gong, Hui; Zhang, Qianqian; Yan, Liang; Wang, Hao

doi:10.1007/s11708-024-0927-7

Front. Energy

2024

DOI: 10.1007/s11708-024-0927-7

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Recent progress in Prussian blue electrode for electrochromic devices

Yongting Zhang,

Wanzhong Li,

Hui Gong

et al.

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Cited by 5 publications

References 113 publications

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High‐Performance Complementary Electrochromic Batteries using Nb₁₈W₁₆O₉₃ by the Synergistic Effects of Aqueous Al³⁺/K⁺ Dual‐Ion

Wu,

Zhang,

Shi

et al. 2024

Angewandte Chemie

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Multivalent ions, especially Al3+ in aqueous electrolyte contributes to higher capacity and color contrast for more sustainable post‐lithium electrochromism and energy storages. However, the lack of suitable cathodic and anodic electrochromic materials is a major challenge for Al‐ion electrochromic batteries, which limits their optical contrast and lifespan. Herein, we report that Wadsley‐Roth phase Nb18W16O93 with open structure achieves Al3+ intercalation/extraction reversibly. The complementary electrochromic energy storage devices based on Nb18W16O93 coupled with Prussian blue using hybrid Al3+/K+ aqueous electrolytes show a fast response, a high capacity and a large coloring efficiency. The superior performances are due to the cations of Al3+ and K+ selectively insert/extract in the electrode of Nb18W16O93 and Prussian blue, respectively. This work provides an effective strategy for high‐performance and low‐cost electrochromic batteries with higher sustainability.

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High‐Performance Complementary Electrochromic Batteries using Nb₁₈W₁₆O₉₃ by the Synergistic Effects of Aqueous Al³⁺/K⁺ Dual‐Ion

Wu,

Zhang,

Shi

et al. 2024

Angewandte Chemie

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show abstract

High‐Performance Complementary Electrochromic Batteries using Nb₁₈W₁₆O₉₃ by the Synergistic Effects of Aqueous Al³⁺/K⁺ Dual‐Ion

Wu,

Zhang,

Shi

et al. 2024

Angew Chem Int Ed

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Evaluating polyanthranilic acid as a polymeric template for the production of Prussian blue nanoclusters

Gilpin,

McCormick,

McMath

et al. 2024

J Mater Sci

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The electropolymerization of anthranilic acid (2-aminobenzoic acid) has been shown to lead to the production of a redox polymer functionalized with carboxylate groups capable of complexing metal ions. The polymer was exploited as a means of capturing ferric ion from solution with the iron decorated polymer chains used as seeding points for the formation of Prussian blue (PB). Nanoclusters of PB were dispersed throughout the three-dimensional polymer matrix with deposition achieved through direct electrochemical means or via a dip process. The latter exploited the chemical combination of Fe(III) + Ferrocyanide to yield PB allowing its dispersal of the PB throughout the polymer film. The polymer film and its subsequent modification have been characterized by electron microscopy, X-ray analysis, Raman spectroscopy and electrochemical analysis. The stability toward peroxide has also been explored. Graphical Abstract

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Recent progress in Prussian blue electrode for electrochromic devices

Cited by 5 publications

References 113 publications

High‐Performance Complementary Electrochromic Batteries using Nb₁₈W₁₆O₉₃ by the Synergistic Effects of Aqueous Al³⁺/K⁺ Dual‐Ion

High‐Performance Complementary Electrochromic Batteries using Nb₁₈W₁₆O₉₃ by the Synergistic Effects of Aqueous Al³⁺/K⁺ Dual‐Ion

High‐Performance Complementary Electrochromic Batteries using Nb₁₈W₁₆O₉₃ by the Synergistic Effects of Aqueous Al³⁺/K⁺ Dual‐Ion

Evaluating polyanthranilic acid as a polymeric template for the production of Prussian blue nanoclusters

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Product

Resources

About

Recent progress in Prussian blue electrode for electrochromic devices

Cited by 5 publications

References 113 publications

High‐Performance Complementary Electrochromic Batteries using Nb18W16O93 by the Synergistic Effects of Aqueous Al3+/K+ Dual‐Ion

High‐Performance Complementary Electrochromic Batteries using Nb18W16O93 by the Synergistic Effects of Aqueous Al3+/K+ Dual‐Ion

High‐Performance Complementary Electrochromic Batteries using Nb18W16O93 by the Synergistic Effects of Aqueous Al3+/K+ Dual‐Ion

Evaluating polyanthranilic acid as a polymeric template for the production of Prussian blue nanoclusters

Contact Info

Product

Resources

About

High‐Performance Complementary Electrochromic Batteries using Nb₁₈W₁₆O₉₃ by the Synergistic Effects of Aqueous Al³⁺/K⁺ Dual‐Ion

High‐Performance Complementary Electrochromic Batteries using Nb₁₈W₁₆O₉₃ by the Synergistic Effects of Aqueous Al³⁺/K⁺ Dual‐Ion

High‐Performance Complementary Electrochromic Batteries using Nb₁₈W₁₆O₉₃ by the Synergistic Effects of Aqueous Al³⁺/K⁺ Dual‐Ion