Superhydrophobic textiles with multifunctional characteristics
are highly desired and have attracted tremendous research attention.
This research employs a simple dip-coating method to obtain a fluorine-free
silica-based superhydrophobic and superoleophilic cotton fabric. Pristine
cotton fabric is coated with SiO2 nanoparticles and octadecylamine.
SiO2 nanoparticles are anchored on the cotton fabric to
increase surface roughness, and octadecyl amine lowers the surface
energy, turning the hydrophilic cotton fabric into superhydrophobic.
The designed cotton fabric exhibits a water contact angle of 159°
and a sliding angle of 7°. The prepared cotton fabric is characterized
by attenuated total reflectance-fourier transform infrared spectroscopy,
X-ray diffraction, atomic force microscopy, scanning electron microscopy,
and energy-dispersive X-ray spectroscopy. In addition, the coated
fabric reveals excellent features, including mechanical and chemical
stability, superhydrophobicity, superoleophilicity, and the self-cleaning
ability. SiO2 nanoparticles and octadecylamine-coated cotton
fabric demonstrate exceptional oil–water separation and wastewater
remediation performance by degrading the methylene blue solution up
to 89% under visible light. The oil–water separation ability
is tested against five different oils with more than 90% separation
efficiency. This strategy has the advantages of low-cost precursors,
a simple and scalable coating method, enhanced superhydrophobicity
and superoleophilicity, self-cleaning ability, efficient oil–water
separation, and exceptional wastewater remediation performance.