Recent progress in tailoring the properties of inorganic CsPbX₃ perovskites with functional organic compounds: a route to enhanced efficiency and operational stability in CsPbX₃-based photovoltaics

Abstract

Due to their superior thermostability, inorganic CsPbX3 halide perovskites are considered the most promising photoabsorbers for commercially viable photovoltaic devices compared to their organic–inorganic analogs, which have demonstrated very impressive solar cell efficiency evolution in a few years though.

Recent Progress in Perovskite Materials Using Diammonium Organic Cations Toward Stable and Efficient Solar Cell Devices: Dion–Jacobson

“…[ 109–111 ] Furthermore, this material raises some black‐phase instability issues at room temperature, which leads to the degradation of the perovskite phase from black to yellow. [ 112–114 ]…”

“…[109][110][111] Furthermore, this material raises some black-phase instability issues at room temperature, which leads to the degradation of the perovskite phase from black to yellow. [112][113][114] To overcome this problem, many strategies have been developed in the literature, from solvent engineering to dimensional engineering. In this subsection, some studies using the diammonium cations in all-inorganic perovskite solar cells to stabilize the α-phase are reported.…”

Outstanding nonlinear optical properties of all-inorganic perovskite CsPbX3 (X=Cl, Br, I) precursor solutions and polycrystalline films

“… 11 , 12 , 13 The low solubility of the CsX in organic solvent prevents the formation of high-quality thin films, which impulse for their applications in various fields. 14 , 15 , 16 , 17 …”

Improving the thermal resistance of fluorescent CsPb(Br,I) 3 perovskite quantum dots by surface modification with perfluorodecanoic acid

“…CsPbX 3 (X = Cl, Br, I) perovskite quantum dots (QDs) have attracted extensive research attention owing to their excellent properties, including their bandgap (E g ) tunability (by halide composition), narrow luminescence peaks and high photoluminescence (PL) quantum yields (PLQYs) [1,2]. Accordingly, CsPbX 3 QDs have been applied in LEDs [3][4][5][6][7][8][9][10], wide-gamut displays [11][12][13][14], lasers [15][16][17], scintillators [18] and photovoltaic devices [19][20][21][22][23][24]. However, like organic-inorganic perovskite QDs, all-inorganic CsPbX 3 QDs are insufficiently durable for practical use yet.…”