Recent progress in the fabrication of nanostructured zinc-based ternary metal oxides for high-performance lithium-ion batteries

Liao, Wenming; Chen, Haihui; Zeng, Yingying; Liu, Limin

doi:10.1007/s10800-022-01832-5

Cited by 5 publications

(1 citation statement)

References 251 publications

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“…Owing to their high theoretical capacity and good safety, metal oxides, especially transition metal oxides, have been considered promising anodic materials in replacing conventional commercialized graphite anodes [19]. The conversion reaction for most of the transition metal oxides (e.g., Fe 2 O 3 , Fe 3 O 4 , MoO 3 , MnO 2 ) relates to the formation of pure metal and Li 2 O during the primary insertion step and the reversible oxidation of metal after extraction [20][21][22]. Hence, because of the well-utilized oxidation state and multi-electrons involved in the conversion processes, these kinds of transition metal oxide-based electrode materials generally show high reversible capacities and discharging rates.…”

Section: Introductionmentioning

confidence: 99%

Lignin-Based Mesoporous Hollow Carbon@MnO2 Nanosphere Composite as an Anodic Material for Lithium-Ion Batteries

Li,

Huang,

2023

Materials

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The lignin-based mesoporous hollow carbon@MnO2 nanosphere composites (L-C-NSs@MnO2) were fabricated by using lignosulfonate as the carbon source. The nanostructured MnO2 particles with a diameter of 10~20 nm were uniformly coated onto the surfaces of the hollow carbon nanospheres. The obtained L-C-NSs@MnO2 nanosphere composite showed a prolonged cycling lifespan and excellent rate performance when utilized as an anode for LIBs. The L-C-NSs@MnO2 nanocomposite (24.6 wt% of MnO2) showed a specific discharge capacity of 478 mAh g−1 after 500 discharge/charge cycles, and the capacity contribution of MnO2 in the L-C-NSs@MnO2 nanocomposite was estimated ca. 1268.8 mAh g−1, corresponding to 103.2% of the theoretical capacity of MnO2 (1230 mAh g−1). Moreover, the capacity degradation rate was ca. 0.026% per cycle after long-term and high-rate Li+ insertion/extraction processes. The three-dimensional lignin-based carbon nanospheres played a crucial part in buffering the volumetric expansion and agglomeration of MnO2 nanoparticles during the discharge/charge processes. Furthermore, the large specific surface areas and mesoporous structure properties of the hollow carbon nanospheres significantly facilitate the fast transport of the lithium-ion and electrons, improving the electrochemical activities of the L-C-NSs@MnO2 electrodes. The presented work shows that the combination of specific structured lignin-based carbon nanoarchitecture with MnO2 provides a brand-new thought for the designation and synthesis of high-performance materials for energy-related applications.

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Section: Introductionmentioning

confidence: 99%

Lignin-Based Mesoporous Hollow Carbon@MnO2 Nanosphere Composite as an Anodic Material for Lithium-Ion Batteries

Li,

Huang,

2023

Materials

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Recent Progresses of Battery Thermal Management Systems Based on Phase Change Materials

Xiao,

Zhang,

Zhang

et al. 2024

Energy Tech

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Battery thermal management system (BTMS) based on phase change materials (PCMs) is simple in structure while presenting outstanding performance, but the core bottleneck hindering the industrialization of which is the poor performance of PCMs’ pivotal properties. Apart from that, under extreme conditions, single passive phase change temperature‐control technology apparently could not meet the demands. Therefore, modification strategies to improve PCM's pivotal properties suitable for BTMS are thoroughly reviewed. Moreover, the optimization of as‐mentioned passive systems by integrating them with other active heating or cooling devices to obtain advanced active and passive full‐temperature responsive capability is also summarized. Profound opinions concerning about the prospect and challenges of PCM‐BTMS are given. It is expected to provide some innovative ideas for the advancement of such promising technology.

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ZIF-8-derived ultrasmall ZnO nanoparticles embedded in porous carbon nanocage as anode material for lithium-ion batteries

Zhang,

Ding,

et al. 2024

Ionics

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Recent progress in the fabrication of nanostructured zinc-based ternary metal oxides for high-performance lithium-ion batteries

Cited by 5 publications

References 251 publications

Lignin-Based Mesoporous Hollow Carbon@MnO2 Nanosphere Composite as an Anodic Material for Lithium-Ion Batteries

Lignin-Based Mesoporous Hollow Carbon@MnO2 Nanosphere Composite as an Anodic Material for Lithium-Ion Batteries

Recent Progresses of Battery Thermal Management Systems Based on Phase Change Materials

ZIF-8-derived ultrasmall ZnO nanoparticles embedded in porous carbon nanocage as anode material for lithium-ion batteries

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