Recent progress of Si-based anodes in the application of lithium-ion batteries

Xia, Xin; Qian, Xingyue; Chen, Chao; Li, Weiyan; He, Dafang; He, Guangyu; Chen, Haiqun

doi:10.1016/j.est.2023.108715

Cited by 26 publications

(6 citation statements)

References 158 publications

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“…The appeal of Si as an anode material in ASSBs stems from its ready availability, non-toxic nature, and remarkable theoretical capacity, making it a competitive candidate in the pursuit of next-generation battery technology [ 95 ]. However, it is essential to acknowledge certain limitations associated with Si-based anodes, including concerns related to mechanical integrity, limited electrical conductivity, and cycling lifespan [ 96 , 97 ]. These challenges underscore the ongoing efforts in material modification and engineering to harness Si’s full potential while addressing its drawbacks in advanced battery systems.…”

Section: Electrode Materials For Ssbsmentioning

confidence: 99%

Technological Advances and Market Developments of Solid-State Batteries: A Review

Thomas,

Mahdi,

Lemaire

et al. 2024

Materials

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Batteries are essential in modern society as they can power a wide range of devices, from small household appliances to large-scale energy storage systems. Safety concerns with traditional lithium-ion batteries prompted the emergence of new battery technologies, among them solid-state batteries (SSBs), offering enhanced safety, energy density, and lifespan. This paper reviews current state-of-the-art SSB electrolyte and electrode materials, as well as global SSB market trends and key industry players. Solid-state electrolytes used in SSBs include inorganic solid electrolytes, organic solid polymer electrolytes, and solid composite electrolytes. Inorganic options like lithium aluminum titanium phosphate excel in ionic conductivity and thermal stability but exhibit mechanical fragility. Organic alternatives such as polyethylene oxide and polyvinylidene fluoride offer flexibility but possess lower ionic conductivity. Solid composite electrolytes combine the advantages of inorganic and organic materials, enhancing mechanical strength and ionic conductivity. While significant advances have been made for composite electrolytes, challenges remain for synthesis intricacies and material stability. Nuanced selection of these electrolytes is crucial for advancing resilient and high-performance SSBs. Furthermore, while global SSB production capacity is currently below 2 GWh, it is projected to grow with a >118% compound annual growth rate by 2035, when the potential SSB market size will likely exceed 42 billion euros.

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Section: Electrode Materials For Ssbsmentioning

confidence: 99%

Technological Advances and Market Developments of Solid-State Batteries: A Review

Thomas,

Mahdi,

Lemaire

et al. 2024

Materials

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“…Restricted by serious volume expansion and low conductivity, the practical application of silicon (Si) has been impeded. , To address these challenges, the utilization of Si/C composite material emerges as a promising solution. , On the one hand, the incorporation of carbon material with excellent conductivity can effectively promote rapid electrochemical reactions. , On the other hand, carbon material can act as a buffer to mitigate the impact of volume expansion. , In order to obtain a Si/C composite material with an exceptional electrochemical performance, several key factors must be carefully considered. For instance, Si should be uniformly dispersed within carbon material to minimize agglomeration.…”

Section: Introductionmentioning

confidence: 99%

Reinforced Interfacial Interaction between Si and Graphite To Improve the Cyclic Stability of Lithium-Ion Batteries

Dong,

Liu,

et al. 2024

ACS Appl. Mater. Interfaces

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Preparing Si/C composite material with uniformly dispersed Si particles and stable electrode structure remains a huge challenge. In this study, a Si/C composite material with reinforced interfacial interaction (Si&AG) was successfully synthesized. Utilizing the HF-plasma technique, the metallurgical Si with large particle size was evaporated and nucleated, resulting in nanocrystallization and uniform dispersion onto the graphite surface. More importantly, a robust but thin SiC layer formed at the contact region ensures a steadfast adhesion of Si onto graphite. As anode for lithium-ion batteries, Si&AG exhibits a remarkable ICE of 87.9% and an impressive capacity retention of 78.1% after 500 cycles at 0.1 A g −1 . Even under high current densities, it consistently demonstrates a remarkable electrochemical performance (149.6 mAh g −1 at 3 A g −1 ). These exceptional properties can be attributed to the reinforced interfacial interaction facilitated by a robust but thin SiC layer, which endows the electrode with a stable structure and consequently performs excellent electrochemical performances.

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“…However, with the rapid advancement of technology and the ever-growing energy demands of humanity, the constraints of lithium-ion batteries, for instance, limited energy density, pollution concerns, and inadequate security conditions during energy storage, have greatly hindered their development. 7 The emergence of solid-state batteries, characterized by increasing energy density and enhanced security features, holds the promise of overcoming the constraints faced by traditional liquid lithium-ion batteries. 8−10 Among the various types of solid-state batteries, those on the basis of oxide solid electrolytes (SEs) show tremendous potential and are poised to become the new-age technology for lithium-ion batteries.…”

Section: Introductionmentioning

confidence: 99%

“…Lithium-ion battery technology, heralded as a brilliant new star in the constellation of modern human civilization, plays an indispensable role in the domain of energy. − Since its inception, lithium-ion batteries have garnered global visibility and favor because of their high energy density, long lifespan, and stability, establishing themselves as the preferred power solution for portable electronic devices such as smartphones, laptops, and even electric vehicles. However, with the rapid advancement of technology and the ever-growing energy demands of humanity, the constraints of lithium-ion batteries, for instance, limited energy density, pollution concerns, and inadequate security conditions during energy storage, have greatly hindered their development . The emergence of solid-state batteries, characterized by increasing energy density and enhanced security features, holds the promise of overcoming the constraints faced by traditional liquid lithium-ion batteries. − Among the various types of solid-state batteries, those on the basis of oxide solid electrolytes (SEs) show tremendous potential and are poised to become the new-age technology for lithium-ion batteries .…”

Section: Introductionmentioning

confidence: 99%

Review on Interface Issues between a Garnet Li₇La₃Zr₂O₁₂ Solid Electrolyte and Li Anode: Advances and Perspectives

Wang,

Li,

et al. 2024

Energy Fuels

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In the pursuit of advancements within the realm of solid-state lithium metal batteries, considerable attention has been directed toward the garnet-type Li 7 La 3 Zr 2 O 12 (LLZO) material owing to its exceptional lithium stability, elevated ionic conductivity at room temperature, compatibility with high operating voltages, and environmentally friendly low-cost production methodologies. Despite these merits, the widespread utilization of LLZO in conjunction with a lithium anode is significantly impeded by the emergence of high interfacial resistance and interface lithium dendrite growth issues. When these challenges are addressed, this paper comprehensively examines the mechanistic underpinnings of interface issues arising from the interaction between LLZO and a lithium anode. Furthermore, it surveys the latest advancements and improvement methodologies employed to mitigate these concerns, aiming to propel the advancement of solid-state battery technology.

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Recent progress of Si-based anodes in the application of lithium-ion batteries

Cited by 26 publications

References 158 publications

Technological Advances and Market Developments of Solid-State Batteries: A Review

Technological Advances and Market Developments of Solid-State Batteries: A Review

Reinforced Interfacial Interaction between Si and Graphite To Improve the Cyclic Stability of Lithium-Ion Batteries

Review on Interface Issues between a Garnet Li₇La₃Zr₂O₁₂ Solid Electrolyte and Li Anode: Advances and Perspectives

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Recent progress of Si-based anodes in the application of lithium-ion batteries

Cited by 26 publications

References 158 publications

Technological Advances and Market Developments of Solid-State Batteries: A Review

Technological Advances and Market Developments of Solid-State Batteries: A Review

Reinforced Interfacial Interaction between Si and Graphite To Improve the Cyclic Stability of Lithium-Ion Batteries

Review on Interface Issues between a Garnet Li7La3Zr2O12 Solid Electrolyte and Li Anode: Advances and Perspectives

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Product

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Review on Interface Issues between a Garnet Li₇La₃Zr₂O₁₂ Solid Electrolyte and Li Anode: Advances and Perspectives