Recent progress on garnet-type oxide electrolytes for all-solid-state lithium-ion batteries

Fluorine-Doped Li7La3Zr2O12 Fiber-Based Composite Electrolyte for Solid-State Lithium Batteries with Enhanced Electrochemical Performance

“…8,9 Among ISEs, the garnet-type electrolyte Li 7 La 3 Zr 2 O 12 (LLZO) has been widely investigated due to its high ionic conductivity of ∼10 −4 S cm −1 at room temperature and high stability against lithium metal anodes. 10 The crystal structure of cubic LLZO consists of two parts, the ZrO 6 octahedron connected to the LaO 8 dodecahedron to form a three-dimensional (3D) framework structure, with Li1 and Li2 atoms occupying the tetrahedral interstitials (LiO 4 , 24 d) and the distorted octahedral interstitials (LiO 6 , 96 h), respectively. 11,12 The LiO 4 and LiO 6 share the face, which provides the short lithium transport pathway.…”

“…In addition, SSEs need to remain electrochemically stable toward the lithium metal and cathode; otherwise, this will result in a loss of battery capacity and life . Based on the differences in chemical composition, SSEs are categorized as inorganic solid electrolytes (ISEs) and solid polymer electrolytes (SPEs). , Among ISEs, the garnet-type electrolyte Li 7 La 3 Zr 2 O 12 (LLZO) has been widely investigated due to its high ionic conductivity of ∼10 –4 S cm –1 at room temperature and high stability against lithium metal anodes . The crystal structure of cubic LLZO consists of two parts, the ZrO 6 octahedron connected to the LaO 8 dodecahedron to form a three-dimensional (3D) framework structure, with Li1 and Li2 atoms occupying the tetrahedral interstitials (LiO 4 , 24 d) and the distorted octahedral interstitials (LiO 6 , 96 h), respectively. , The LiO 4 and LiO 6 share the face, which provides the short lithium transport pathway.…”

Materials Development and Potential Applications of Ceramics: New Opportunities and Challenges

“…Bioceramics find applications in medical innovations, such as implants [17] and dental prosthetics [18]. Ceramics are also pivotal in clean energy conversion (e.g., solid oxide fuel cells [19]) and energy storage (e.g., solid-state batteries [20]). Ceramic substrates [21] in catalytic converters aid in automobiles' emission control, while ceramic coatings enhance engine performance and durability [22].…”