Recent progress on hard carbon and other anode materials for sodium-ion batteries

Shafiee, Farah Nabilah; Mohd Noor, Siti Aminah; Mohd Abdah, Muhammad Amirul Aizat; Jamal, Siti Hasnawati; Samsuri, Alinda

doi:10.1016/j.heliyon.2024.e29512

Heliyon

2024

DOI: 10.1016/j.heliyon.2024.e29512

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Recent progress on hard carbon and other anode materials for sodium-ion batteries

Farah Nabilah Shafiee,

Siti Aminah Mohd Noor,

Muhammad Amirul Aizat Mohd Abdah

et al.

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Cited by 3 publications

References 168 publications

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Single-step pyrolysis of Stipa Tenacissima fibers to hard carbon: A potential route for sodium-ion battery anodes

Daoudi,

Kassab,

Chari

et al. 2024

Diamond and Related Materials

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Single-step pyrolysis of Stipa Tenacissima fibers to hard carbon: A potential route for sodium-ion battery anodes

Daoudi,

Kassab,

Chari

et al. 2024

Diamond and Related Materials

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Dual graphitization to fabricate graphitic carbon aerogel for superior sodium-ion storage

Zhang,

et al. 2025

Journal of Alloys and Compounds

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Electron Paramagnetic Resonance Monitoring of Sodium Clustering and Its Effect on the Sodium Storage of Biowaste-Derived Carbons

Kukeva,

Kalapsazova,

Harizanova

et al. 2024

ACS Appl. Energy Mater.

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Biowaste-derived carbons store large amounts of sodium as many competing reactions of adsorption, intercalation, and pore filling take place. Herein, we report electron paramagnetic resonance (EPR) spectroscopy as a comprehensive method to monitor the interaction of sodium with carbons used as electrodes in sodium-ion cells. It is shown that EPR can distinguish signals due to sodium intercalation and sodium cluster growth. Applying the correlation between the EPR line width and the metallic particle dimension, the sodium clusters are quantified regarding their size. In terms of the EPR, we discuss the sodiation mechanism and sodium storage performance of carbons derived from spent coffee grounds. The smallest sodium clusters (below 2 nm) are formed on closedpore carbons at a potential of 0.01 V, while the largest clusters (around 200 nm) occur on hydrogen-rich carbons at 0.05 V at the earliest. The small sodium clusters generated at around 0.01 V give extra capacity, while sodium intercalation occurring between 0.5 and 0.1 V ensures good cycle stability.

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Recent progress on hard carbon and other anode materials for sodium-ion batteries

Cited by 3 publications

References 168 publications

Single-step pyrolysis of Stipa Tenacissima fibers to hard carbon: A potential route for sodium-ion battery anodes

Single-step pyrolysis of Stipa Tenacissima fibers to hard carbon: A potential route for sodium-ion battery anodes

Dual graphitization to fabricate graphitic carbon aerogel for superior sodium-ion storage

Electron Paramagnetic Resonance Monitoring of Sodium Clustering and Its Effect on the Sodium Storage of Biowaste-Derived Carbons

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