“…2D materials have intrigued great attentions over the years since their fantastic characteristics are close to and even superior than their bulk counterparts, for instance, excellent mechanical properties, [1][2][3] ultrahigh heat conduction, [4][5][6] unique quantum effects in low dimensions (e.g., superconductivity and quantum hall effect, etc.). [7][8][9][10][11] Since graphene has been successfully pre pared by mechanical exfoliation, [12][13][14] most 2D members have been prepared by the top-down exfoliation of their naturally existed bulk parent materials, for example, mechanical strip ping materials (MoS 2 , hBH, NbSe 2 , and MnBi 2 Te 4 ), [15][16][17] inter faceassisted exfoliation materials (black phosphorene, FeSe, MoS 2 type MZ 2 layer into an InSetype A 2 Z 2 monolayer (Figure 1e). [29] If 2H and 1T phases of MZ 2 and α and β phases of A 2 Z 2 are considered, 4 types of monolayer MA 2 Z 4 nanosheets can be obtained, that is, α i MA 2 Z 4 (i = 1-6), β i MA 2 Z 4 (i = 1-12), γ i MA 2 Z 4 (i = 1-3), and δ i MA 2 Z 4 (i = 1-9).…”