“…Titanium nitrate quantum dots (TiN QDs) were constructed by modifying a solvothermal method [56] reported in our previous work [58], where in this work we increased the ratio of the glycerol and ammonia treatment program to obtain monodispersed ultrasmall TiN QDs. In brief, 500 mg of tetrabutyl titanate (>99%, GC grade, Macklin Inc., Shanghai, China), 12 mL of glycerol (99%, AR grade, Macklin Inc., Shanghai, China), 20 mL of methanol (99.5%, AR grade, Macklin Inc., Shanghai, China), and 12 mL of ethyl ether (99%, AR grade, Macklin Inc., Shanghai, China) were mixed under vigorous stirring for 1 h, followed by a solvothermal process at 150 • C for 15 h. The resultant products were collected via centrifugation with a centrifuge (Thermal Scientific, SORVALL ST 16R, Waltham, MA, USA) at 12,000 rpm for 15 min and washed with ethanol (99.5%, AR grade, Macklin Inc., Shanghai, China) 3 times, followed by drying in a vacuum oven (Memmert, VO500, Schwabach, Germany) at 70 • C overnight.…”