Recent studies on organometallic intramolecular-coordination compounds

Omae, Iwao

doi:10.1016/0010-8545(88)80022-5

Cited by 222 publications

(46 citation statements)

References 121 publications

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“…They are widely used in organic synthesis, organometallic catalysis, and new molecular materials [2,3]. For example, in the palladium-catalyzed carbon-carbon bond and carbon-heteroatom bond forming reactions, palladacycles have shown enormous superiority in many respects due to their ready preparation, facile modification, high activity and comparative stability [3,4].…”

Section: Introductionmentioning

confidence: 99%

Synthesis, characterization and crystal structures of two cis/trans pyridine-cyclopalladated ferrocenylimine complexes

Gong

Zhang

et al. 2007

Transition Met Chem

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Two new pyridine-cyclopalladated ferrocenylimine complexes (2a) and (2b) have been easily prepared from the reaction of halogen-bridged palladacyclic dimer (1a) and (1b) with pyridine in high yields. They were fully characterized by elemental analysis, M.s.-e.s.i., I.r., 1 H-n.m.r. and single-crystal X-ray analysis. Complex (2a) adopts a trans geometry in the solid state, while (2b) is cis. There are altogether four different types of intermolecular hydrogen bonds in their crystals. The impressing features include those intermolecular ClÁ Á ÁCl interactions in (2a) and CHÁ Á ÁPd hydrogen bonds in (2b).

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Section: Introductionmentioning

confidence: 99%

Synthesis, characterization and crystal structures of two cis/trans pyridine-cyclopalladated ferrocenylimine complexes

Gong

Zhang

et al. 2007

Transition Met Chem

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“…Cyclometallated complexes form an important class of organometallic species [1][2][3][4][5][6][7]. Formation of such complexes involves ligand C-H activation.…”

Section: Introductionmentioning

confidence: 99%

Cyclopalladated complexes with N-(benzoyl)-N′-(2,4-dimethoxybenzylidene)hydrazine: syntheses, characterization and structural studies

Das

Pal

2004

Journal of Organometallic Chemistry

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“…During the two last decades, the interest in cyclopalladated compounds derived from N-donor ligands has noticeably increased [19,20].…”

Section: Introductionmentioning

confidence: 99%

Synthesis and characterization of 2-phenylaniline cyclopalladated complexes

Karami

Rizzoli

Rahimi

2011

Transition Met Chem

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Reaction of the dinuclear complex [Pd{j2-N2 0 ,C1-2-(2 0 -NH 2 C 6 H 4 )C 6 H 4 }Cl] 2 (1) with ligands (L = 4-picoline, sym-collidine) gave the six-membered palladacycles [Pd{j2-N2 0 ,C1-2-(2 0 -NH 2 C 6 H 4 )C 6 H 4 }Cl(L)] (2). The complex 1 reacted with AgX (X = CF 3 SO 3 , BF 4 ) and bidentate ligands [L-L = phen (phenanthroline), dppe (bis(diphenylphosphino)ethane), bipy(2,2 0 -bipyridine) and dppp (bis(diphenylphosphino)propane)] giving the mononuclear orthopalladated complexes [Pd{j2-N2 0 ,C1-2-(2 0 -NH 2 C 6 H 4 )C 6 H 4 }(L-L)] (3) [L-L = phen, dppe, bipy and dppp]. These compounds were characterized by physicochemical methods, and the structure of [Pd{j2-N2 0 ,C1-2-(2 0 -NH 2 C 6 H 4 )C 6 H 4 }Cl(L)] (L = sym-collidine) was determined by single-crystal X-ray analysis.

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Recent studies on organometallic intramolecular-coordination compounds

Cited by 222 publications

References 121 publications

Synthesis, characterization and crystal structures of two cis/trans pyridine-cyclopalladated ferrocenylimine complexes

Synthesis, characterization and crystal structures of two cis/trans pyridine-cyclopalladated ferrocenylimine complexes

Cyclopalladated complexes with N-(benzoyl)-N′-(2,4-dimethoxybenzylidene)hydrazine: syntheses, characterization and structural studies

Synthesis and characterization of 2-phenylaniline cyclopalladated complexes

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