Odia character and digits recognition area are vital issues of these days in computer vision. In this paper a Hopfield neural network designe to solve the printed Odia character recognition has been discussed. Optical Character Recognition (OCR) is the principle of applying conversion of the pictures from handwritten, printed or typewritten to machine encoded text version. Artificial Neural Networks (ANNs) trained as a classifier and it had been trained, supported the rule of Hopfield Network by exploitation code designed within the MATLAB. Preprocessing of data (image acquisition, binarization, skeletonization, skew detection and correction, image cropping, resizing, implementation and digitalization) all these activities have been carried out using MATLAB. The OCR, designed a number of the thought accuses non-standard speech for different types of languages. Segmentation, feature extraction, classification tasks is the well-known techniques for reviewing of Odia characters and outlined with their weaknesses, relative strengths. It is expected that who are interested to figure within the field of recognition of Odia characters are described in this paper. Recognition of Odia printed characters, numerals, machine characters of research areas finds costly applications within the banks, industries, offices. In this proposed work we devolve an efficient and robust mechanism in which Odia characters are recognized by the Hopfield Neural Networks (HNN).