The barrel vibrates violently, which will lead to a serious drop in shooting accuracy. To solve this issue, a barrel vibration control method of the paired oblique nozzle dynamic couple is proposed. A pair of inclined nozzle devices are designed on the barrel to fully use the gunpowder gas energy in the chamber during the shooting process. A dynamic couple is generated to balance the turning moment of the barrel weapon. Simultaneously, the recoil force is reduced by exporting the gunpowder gas in the chamber. Therefore, the vibration of the barrel is reduced. Firstly, the internal ballistic two-phase flow model including the gas transient flow model in the vibration control device is modelled based on the internal ballistic theory of two-phase flow. Secondly, the numerical simulation of the weapon launching process is carried out. Thirdly, the rigid-flexible coupling firing dynamics modelling and simulation research is conducted on a 30mm chain gun equipped with a paired oblique nozzle dynamic couple vibration control device. At last, the effects of the device on the continuous firing vibration control of barrel weapons are analyzed. The results show that the vibration reduction efficiency of the inclined nozzle is better than that of the vertical nozzle and the horizontal nozzle. When the angle of the inclined nozzle is 30°, the barrel shows the highest vibration reduction efficiency. The vibration reduction efficiency of each vibration characteristic is 39.2%, 17.1%, 44.8%, and 48.9%, respectively.