2022
DOI: 10.1021/acs.langmuir.2c01940
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Reconfiguration of Langmuir Monolayers of Thermo-Responsive Branched Ionic Polymers with LCST Transition

Abstract: Thermo-responsive ionic polymers have the ability to form adaptive and switchable morphologies, which may offer enhanced control in energy storage and catalytic applications. Current thermoresponsive polymers are composed of covalently attached thermoresponsive moieties, restricting their mobility and global dynamic response. Here, we report the synthesis and assembly at the water−air interface of symmetric and asymmetric amphiphilic thermo-responsive branched polymers with weakly ionically bound arms of amine… Show more

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Cited by 3 publications
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“…These values are comparable to other amphiphilic functionalized POSS reported in the literature. The size and ζ-potential values reveal the effect of the POSS alkyl chain length on their assembly in aqueous solutions due to the varying hydrophobic/hydrophilic balance (Figure a). Specifically, the larger size of POSS-9 is attributed to the enhanced hydrophobicity of the longer alkyl chains that leads to the formation of larger aggregates in aqueous dispersions .…”
Section: Resultsmentioning
confidence: 99%
“…These values are comparable to other amphiphilic functionalized POSS reported in the literature. The size and ζ-potential values reveal the effect of the POSS alkyl chain length on their assembly in aqueous solutions due to the varying hydrophobic/hydrophilic balance (Figure a). Specifically, the larger size of POSS-9 is attributed to the enhanced hydrophobicity of the longer alkyl chains that leads to the formation of larger aggregates in aqueous dispersions .…”
Section: Resultsmentioning
confidence: 99%