Irpinia (Province of Avellino, Campania Region) is a historical–geographical region of Southern Italy inhabited in pre-Roman times by the ancient Samnite tribe of the Irpini, from which the name originates. This area is characterized by both low population density and high naturalness; located on the axial sector of the southern Apennine orogenic chain, the area possesses a complex hilly and mountainous orography, with predominantly agricultural and forest land uses. In this geographical context, there are many relevant geological/geomorphological sites, witnessing a wide geodiversity attributable to complex geological evolution and relief morphogenesis. The extensive bio-geodiversity has thus led to widespread geotourism practices. Irpinia is favored for its beautiful landscapes, rich cultural heritage, and typical small towns, often enhanced by quality certifications; moreover, geotourism activities are often associated with other forms of sustainable tourism. Starting from this geographical framework, the article analyzes eight attractive geosites that represent the geotouristic value of the entire Irpinia area well. The analysis was conducted using well-known qualitative and quantitative assessment methods. The results obtained, emphasizing the salient aspects of geodiversity, can be used in planning the usability of the sites and, more generally, planning for the Irpinian landscape in a geo-ecotouristic sense.