As a means of increasing data capacity, the multilayer optical disc is a promising approach. Because the recording layers in multilayer optical discs must have a high transmittance, they are commonly made of transparent oxide films. Moreover, the recording layer must have sufficient long-term reliability for data archival. In this work, a recording material with high transmittance and long-term reliability for use in super-multilayer discs was investigated. This paper clarifies the recording mechanism of GeBi oxide material and proposes a suitable material design that satisfies the abovementioned characteristics. Furthermore, experimental results of recording on super-multilayer discs based on GeBi oxide recording material are presented.