The adsorption isotherms of azo dyes on a newly synthesized
titania-doped
silica (TdS) aerogel compared to silica aerogels and activated charcoal
(AC) are systematically investigated. Monolithic TdS aerogels were
synthesized by the cogelation process followed by supercritical drying
of tetraethyl orthosilicate (TEOS) as a gel precursor and titanium(IV)
isopropoxide (TTIP) as a metal complex precursor for co-polymerization
in ethanol solvent. An acid–base catalyst was used for the
hydrolysis and condensation of TEOS and TTIP. The effect of Ti4+ doping in a silica aerogel on the mesoporous structure and
the adsorption capacity of methylene blue (MB) and crystal violet
(CV) dyes were evaluated from the UV–vis absorption spectra.
In order to compare the adsorption isotherms, the surface areas of
silica and TdS aerogels were first normalized with respect to AC,
as adsorption is a surface phenomenon. The azo dye equilibrium adsorption
data were analyzed using different isotherm equations and found to
follow the Langmuir adsorption isotherm. The maximum monolayer adsorption
capacities for the adsorbent TdS aerogel normalized with the AC of
the Langmuir isotherm are 131.58 and 159.89 mg/g for MB and CV dyes,
respectively. From the Langmuir curve fitting, the Q
max value of the TdS aerogel was found to increase by
1.22-fold compared to AC, while it increased 1.25–1.53-fold
compared to the silica aerogel. After four cycles, regeneration efficiency
values for MB and CV dyes are about 84 and 80%, respectively. The
study demonstrates the excellent potential and recovery rate of silica
and TdS aerogel adsorbents in removing dyes from wastewater. The pore
volume and average pore size of the new aerogel, TdS, were found to
be lower than those of the silica aerogel. Thus, a new TdS aerogel
with a high capacity of adsorption of azo dyes is successfully achieved.