Recycling of Carbone Oxides (Co, Co2) Conversion Into Methanol at Atmospheric Pressure Over Mechanochemical Achtivated Cuo-Zno-Al2o3 Catalyst

Abstract

The catalytic process for methanol production by synthesis gas conversion under the conditions of mechanochemical activation (MCA) of copper-zinc-aluminum oxide catalyst in the temperature range 160–280 °C at a pressure of 0.1 MPa are investigated. The use of mechanical action force is one of the promising ways to improve the activity of heterogeneous catalysts designed to simplify the manufacturing process lines, improving the efficiency of catalytic processes and reduce the cost of the target product. Given the importance of technology for methanol production on copper-zinc-aluminum oxide catalysts and high demand for methanol in the world [1–3], clarification of the peculiarities of the process of methanol production by synthesis gas conversion in terms of mechanical load on the catalyst is important in scientific and applied ways. It is established that specific catalytic activity, performance of methanol synthesis catalyst and the conversion of initial reagents are increased in the conditions of mechanochemical activation, because of the increasing concentration of defects and formation of additional active centers. It is revealed that mechanochemical treatment of copper-zinc-aluminum oxide catalyst can reduce reaction initiation temperature and optimum temperature synthesis by 20–30 °C, and increase the maximum performance of the catalytic system. Increase of the catalyst activity under mechanical stress is explored by increase of defect concentration of crystal lattice of the catalyst, as confirmed by the tests of catalyst surface structure by scanning electron microscopy, Raman spectroscopy and X-ray analysis. A new effective method for synthesis gas conversion into the methanol under conditions of mechanochemical activation of the catalyst can be used in industry as an alternative to methanol production at high pressures.