Recycling of Wastewater Containing Iron-Complex Cyanides Using UV Photodecomposition and UV Ozone Oxidation in Combination with an Ion-Exchange Resin Method

Abstract

Wastewater contaminated with iron-complex cyanides was processed by UV photodecomposition accompanied by an iron elimination process using an iron-adsorbent. The wastewater processed by UV photodecomposition was oxidized by ozone combined with UV irradiation. The treated water was deionized by an ion-exchange resin method. This combined processes further increased the production of the pure water volume compared to a single process using an ion-exchange resin. The technique developed in this study can be summarized as follows. First, the iron-complex cyanides in plating wastewater were converted into aquapentacyanoferrate(III) [Fe(CN)5(H2O)]3− ion. Following the application of UV irradiation, it was decomposed into iron and cyanide (CN−) ion. The iron was removed from the water in the form of Fe(OH)3 by processing the wastewater with ozone and an iron-adsorbent. The CN− ion was oxidized to the cyanate (OCN−) form by UV ozone oxidation in a relatively short time. The processed water was de-ionized by passing through cation and anion-exchange resins. The deionized water could be reused as rinsing water in a plating process. The results reported here suggest that wastewater contaminated with chemically stable iron-complex cyanides can be effectively recycled.

Removal of aqueous cyanide with strongly basic ion-exchange resin

“…[1] Ultraviolet photodecomposition of CN − was reported to be very effective. [40] Microbial processes [7,41,42] and phytoremediation [3,[43][44][45] for CN − removal have achieved varying degrees of success. Natural and synthetic polymers and copolymers [46] and liquid membrane technology [47] reportedly worked well for CN − removal and recovery.…”