Red phosphorus encapsulated in porous carbon derived from cigarette filter solid waste as a promising anode material for lithium-ion batteries

Wang, Qian; Lian, Peichao; Wang, Bo; Tang, Yongwei; Liu, Honghong; Mei, Yi

doi:10.1007/s11581-018-2487-5

Cited by 13 publications

(7 citation statements)

References 58 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…After the first cycle, the two peaks shift to ∼0.7 and ∼0.27 V, respectively, which may be due to the activation . In the next anodic scan, the peaks centered at 1.27 V probably relate to the reversible deintercalation of lithium ions with fully charged Li 3 P converting to Li x P ( x = 1–3). , Moreover, the corresponding plateaus can also be observed in all of GCD curves at 0.05 A g –1 , as shown in Figure B. In the first cycle, the HPRP-36 electrode delivers the discharge and charge capacities of 3142 and 2438 mA h g –1 , respectively, with an initial Coulombic efficiency (CE) of 77.6%.…”

Section: Results and Discussionmentioning

confidence: 85%

Green, Template-Less Synthesis of Honeycomb-like Porous Micron-Sized Red Phosphorus for High-Performance Lithium Storage

et al. 2021

View full text Add to dashboard Cite

Large-volume-expansion-induced material pulverization severely limits the electrochemical performance of high-capacity red phosphorus (RP) in alkali-ion batteries. Honeycomb-like porous materials can effectively solve the issues due to their abundant interconnected pore structures. Nevertheless, it is difficult and greatly challenging to fabricate a honeycomb-like porous RP that has not yet been fabricated via chemical synthesis. Herein, we successfully fabricate a honeycomb-like porous micron-sized red phosphorus (HPRP) with a controlled pore structure via a large-scale green and templateless hydrothermal strategy. It is demonstrated that dissolved oxygen in the solution can accelerate the destruction of P9 cages of RP, thus forming abundant active defects with a faster reaction rate, so the fast corrosion forms the honeycomb-like porous structure. Owing to the free volume, interconnected porous structure, and strong robustness, the optimized HPRP-36 can mitigate drastic volume variation and prevent pulverization during cycling resulting in tiny particle-level outward expansion, demonstrated by in situ TEM and ex situ SEM analysis. Thus, the HPRP-36 anode delivers a large reversible capacity (2587.4 mAh g −1 at 0.05 A g −1 ) and long-cycling stability with over 500 cycles (∼81.9% capacity retention at 0.5 A g −1 ) in lithium-ion batteries. This generally scalable, green strategy and deep insights provide a good entry point in designing honeycomb-like porous micron-sized materials for highperformance electrochemical energy storage and conversion.

show abstract

Section: Results and Discussionmentioning

confidence: 85%

Green, Template-Less Synthesis of Honeycomb-like Porous Micron-Sized Red Phosphorus for High-Performance Lithium Storage

et al. 2021

View full text Add to dashboard Cite

show abstract

“…It should be noted that much attention is being given to red phosphorus/carbon composites for Li-ion batteries [423][424][425][426][427][428][429][430]. However, this area of investigation is out of the scope of the present review since phosphorus is not bound to the carbons in such composites.…”

Section: Li-ion Batteriesmentioning

confidence: 95%

Phosphorus-containing carbons: Preparation, properties and utilization

Puziy

Poddubnaya

Gawdzik

et al. 2020

Carbon

127

View full text Add to dashboard Cite

“…RP nanoparticles were evenly distributed within porous carbon (PC) by Wang et al using the evaporation condensation process, and they were then synthesized into composite materials. [57] Due to the excellent conductivity and rich mesoporous structure of porous carbon, it can not only improve overall conductivity but also alleviate the problem of volume expansion. Therefore, the composite material exhibits excellent lithium storage cycling stability (355 mAh g À 1 at 1 A g À 1 ).…”

Section: Evaporation Condensation Methodsmentioning

confidence: 99%

“…Therefore, the composite material exhibits excellent lithium storage cycling stability (355 mAh g À 1 at 1 A g À 1 ). [57] The main drawback of the evaporation/condensation method is that phosphorus vapor condenses at the reactor wall, causing pollution and fire hazards, and is difficult to clean with commonly used solvents such as distilled water and ethanol. [58] In addition, further annealing and toxic CS 2 washing are required for the subsequent processing of the product to avoid WP impurities, [59] which will increase the preparation risk.…”

Section: Evaporation Condensation Methodsmentioning

confidence: 99%

Challenges and Prospects of Phosphorus‐based Anode Materials for Secondary Batteries

Dong,

Wang,

Huang

et al. 2023

Batteries & Supercaps

View full text Add to dashboard Cite

The research of new electrode materials is vital, among which anode materials have a significant role in the improvement of the overall energy density of batteries. Phosphorus‐based anode materials show tremendous potential in the exploration of anode materials due to their high theoretical capacity, natural abundance, and environmental friendliness. In this review, we sum up the latest research progress of red phosphorus‐based, black phosphorus‐based, and transition metal phosphide‐based anode materials for lithium‐ion batteries (LIBs) and sodium‐ion batteries (SIBs). The features of the phosphorus‐based materials, the preparation methods, and the advantages/disadvantages are introduced, as well as the electrochemical storage mechanism of LIBs and SIBs. On this basis, the problems of phosphorus‐based anode materials are considered and analyzed in depth. and improvement strategies are proposed. Finally, the directions that phosphorus‐based materials will take in the future are examined. This paper is intended to advance knowledge of phosphorus‐based anode materials among researchers and to offer some recommendations for using such materials in LIBs and SIBs.

show abstract

Red phosphorus encapsulated in porous carbon derived from cigarette filter solid waste as a promising anode material for lithium-ion batteries

Cited by 13 publications

References 58 publications

Green, Template-Less Synthesis of Honeycomb-like Porous Micron-Sized Red Phosphorus for High-Performance Lithium Storage

Green, Template-Less Synthesis of Honeycomb-like Porous Micron-Sized Red Phosphorus for High-Performance Lithium Storage

Phosphorus-containing carbons: Preparation, properties and utilization

Challenges and Prospects of Phosphorus‐based Anode Materials for Secondary Batteries

Contact Info

Product

Resources

About