This study aimed to map and assess the environmental degradation caused by unmanaged municipal solid waste disposal at the Alaro municipal dumpsite in Southwestern Nigeria, with a focus on leachate contamination. Electrical resistivity imaging (ERI) was applied to define the subsurface geology of the area using five resistivity profiles acquired with a dipole-dipole electrode configuration. Each electrode transect spanned 100 meters with dipole spacings ranging from 2 m to 12 m. Analysis of the uncontaminated segment of the subsurface geology revealed a three-layered geo-electric (lithologic) succession, with resistivity ranges characteristic of loose alluvium, hybrid stratum, and faulted sandstone. Significant decreases in resistivity values, from 3 Ωm to 182 Ωm, were observed around and within the dumpsite, indicating extensive surface contamination by leachate. Three contamination zones were further characterized as leachate-saturated, leachate-concentrated, and leachate-infiltrated sands. In the study area, leachate infiltration extended to a depth of 20 meters, with a marked resistivity contrast between clean and contaminated segments. The likelihood of a normal fault along the control profile further justify leachate migration concerns, highlighting the severity of environmental pollution within the Quaternary sand formation. The contaminated segment poses a significant environmental hazard, that requires immediate mitigation action. Waste recycling, biomass energy generation, and the application of geotextile materials should be prioritized to remediate the dumpsite.