Redox-Active Thiocarbonyl Auxiliaries in Ni-Catalyzed Cross-Couplings of Aliphatic Alcohols

Monteith, John J.; Rousseaux, Sophie A. L.

doi:10.1021/acs.accounts.3c00541

Acc. Chem. Res.

2023

DOI: 10.1021/acs.accounts.3c00541

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Redox-Active Thiocarbonyl Auxiliaries in Ni-Catalyzed Cross-Couplings of Aliphatic Alcohols

John J. Monteith,

Sophie A. L. Rousseaux

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2025

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Photocatalytic Deoxygenative Alkylation with Alcohols via Xanthates or Thionocarbonates

Luo,

Chen,

2025

Asian J Org Chem

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Recent advancements in photocatalytic strategies have expanded the range of alkylating agents, including alkyl carboxylic acids and saturated hydrocarbons. Notably, alcohols are preferred for their availability, stability, and safety compared to traditional alkylating reagents such as alkyl halides. This review summarizes recent developments in photocatalytic deoxygenative alkylation using alcohols, specifically through the formation of xanthates or thionocarbonates.

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Photocatalytic Deoxygenative Alkylation with Alcohols via Xanthates or Thionocarbonates

Luo,

Chen,

2025

Asian J Org Chem

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Redox-Active Thiocarbonyl Auxiliaries in Ni-Catalyzed Cross-Couplings of Aliphatic Alcohols

Cited by 1 publication

References 54 publications

Photocatalytic Deoxygenative Alkylation with Alcohols via Xanthates or Thionocarbonates

Photocatalytic Deoxygenative Alkylation with Alcohols via Xanthates or Thionocarbonates

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